CAS No.1067-53-4,Vinyl tris(2-methoxyethoxy) silane Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	1067-53-4
Name:	Vinyl tris(2-methoxyethoxy) silane

Formula:	C₁₁H₂₄O₆Si
Molecular Weight:	280.393
Synonyms:	Silane,tris(2-methoxyethoxy)vinyl- (6CI,7CI,8CI);A 172 (coupling agent);Dynasylan VTMOEO;GF 58;KBC 1003;KH 172;NSC 78465;NUCA 172;SH 6082;SZ6082;Silane A 172;Silox VS 924;Silquest A 172;Struktol SCA 972;Tris(2-methoxyethoxy)vinylsilane;Tris(b-methoxyethoxy)vinylsilane;U613;UNC-A 172;V 5000;VTMOEO;VTS-ME;Vinyltri(b-methoxyethoxy)silane;Vinyltris(2-methoxyethoxy)silane;Vinyltris(b-methoxyethoxy)silane;WD 27;Z 6082;Z 6172;Tris(2-methoxyethoxy)(vinyl)silane;Tris(methoxyethoxy)vinylsilane;
EINECS:	213-934-0
Density:	1.004 g/cm³
Melting Point:	-30 °C
Boiling Point:	289.5 °C at 760 mmHg
Flash Point:	104.8 °C
Solubility:	REACTS
Appearance:	COA
Hazard Symbols:	Xn,T
Risk Codes:	36-62-61-20/21/22
Safety:	26-53-45-36/37/39
Transport Information:	UN 1993
PSA:	55.38000
LogP:	0.63950

Synthetic route

: 2768-02-7
(vinyl)trimethoxylsilane

: 109-86-4
2-methoxy-ethanol

: 1067-53-4
tris(2-methoxy ethoxy)-vinyl silane

Conditions

Conditions	Yield
With potassium aluminum sulfate at 70 - 80℃; for 2h; Reagent/catalyst;	99.5%

: 109-86-4
2-methoxy-ethanol

: 75-94-5
trichlorovinylsilane

: 1067-53-4
tris(2-methoxy ethoxy)-vinyl silane

Conditions

Conditions	Yield
byproducts: HCl; addn. of a small excess of CH3OCH2CH2OH to boiling (CH2CH)SiCl3; boiling til formation of HCl stops;;	46%

: 109-86-4
2-methoxy-ethanol

: 78-08-0
Triethoxyvinylsilane

A: 1067-53-4
tris(2-methoxy ethoxy)-vinyl silane

B: di(ethoxy)(2-methoxyethoxy)(vinyl)silane

C: ethoxydi[2-methoxyethoxy](vinyl)silane

Conditions

Conditions	Yield
With CBV 780 at 110℃; for 0.0833333h; Microwave irradiation;

...Expand

: 1067-53-4
tris(2-methoxy ethoxy)-vinyl silane

: 696-62-8
para-iodoanisole

: 637-69-4
4-Methoxystyrene

Conditions

Conditions	Yield
With sodium hydroxide; 4-hydroxyacetophenone oxime-derived palladacycle In water for 3h; Hiyama reaction; Heating;	79%

: 1067-53-4
tris(2-methoxy ethoxy)-vinyl silane

: 90-14-2
1-Iodonaphthalene

: 826-74-4
1-vinylnaphthalene

Conditions

Conditions	Yield
With sodium hydroxide; 4-hydroxyacetophenone oxime-derived palladacycle In water at 120℃; for 0.166667h; Hiyama reaction; microwave irradiation;	73%

: 1067-53-4
tris(2-methoxy ethoxy)-vinyl silane

: 99-90-1
para-bromoacetophenone

: 10537-63-0
1-(4-vinylphenyl)ethanone

Conditions

Conditions	Yield
With sodium hydroxide; palladium diacetate In water at 120℃; for 0.166667h; microwave irradiation;	70%

: 1067-53-4
tris(2-methoxy ethoxy)-vinyl silane

: 110590-81-3
N,N'-bis(1-ethylpropyl)-3,4:9,10-perylenebis(dicarboximide)

: 1361061-50-8
N,N'-bis(3-pentyl)-2,5,8,11-tetrakis{2-[tri(2-methoxyethoxy)silyl]ethyl}perylene-3,4:9,10-tetracarboxylic acid bisimide

Conditions

Conditions	Yield
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In 1,3,5-trimethyl-benzene at 160℃; for 60h; Inert atmosphere;	64%

: 998-30-1
Triethoxysilane

: 1067-53-4
tris(2-methoxy ethoxy)-vinyl silane

: C17H40O9Si2

Conditions

Conditions	Yield
With ruthenium(III) 2,4-pentanedionate at 120℃; for 6h;	54%

: 1067-53-4
tris(2-methoxy ethoxy)-vinyl silane

: 1361061-51-9
N,N'-bis[2-(2-methoxyethoxy)ethyl]perylene-3,4:9,10-tetracarboxylic acid bisimide

: 1361061-52-0
N,N'-bis[2-(2-methoxyethoxy)ethyl]-2,5,8,11-tetrakis{2-[tris(2-methoxyethoxy)silyl]ethyl}perylene-3,4:9,10-tetracarboxylic acid bisimide

Conditions

Conditions	Yield
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In 1,3,5-trimethyl-benzene at 160℃; for 48h; Inert atmosphere;	7%

: 14040-11-0
tungsten hexacarbonyl

: 1067-53-4
tris(2-methoxy ethoxy)-vinyl silane

A: 870299-13-1
[W(CO)5(η2-tris(2-methoxyethyloxy)vinylsilane)]

B: 870299-14-2
trans-[W(CO)4(η2-tris(2-methoxyethyloxy)vinylsilane)2]

Conditions

Conditions	Yield
In n-heptane byproducts: CO; Irradiation (UV/VIS); under N2 atm. using Schlenk techniques; soln. of W(CO)6 and vinylsilane in n-heptane irradiated at room temp. using 200 W high pressure Hg lamp for 1-3 h; solvent removed (vac., room temp.); monitored by NMR and IR spectroscopy; sepn. was possible by slow fractional sublimation in vac. at 20-60°C;

...Expand

Raw Materials

75-94-5

109-86-4

Downstream Products

826-74-4

637-69-4

Total:116 Page 1 of 4 1 2 3 4 Next>>

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Chemistry

Molecular Structure:
Molecular Formula: C₁₁H₂₄O₆Si
Molecular Weight: 280.3902
IUPAC Name: Ethenyl-tris(2-methoxyethoxy)silane
Synonyms of Tris(methoxyethoxy)vinylsilane (CAS NO.1067-53-4): (Tris(p-methoxyethoxy))vinylsilane ; 4-04-00-04257 (Beilstein Handbook Reference) ; A 172 ; BRN 1795316 ; EINECS 213-934-0 ; GF 58 ; NSC 78465 ; NUCA 172 ; Prosil 248 ; Q 174 ; SH 6030 ; Silicone A-172 ; Tris(2-methoxyethoxy)vinylsilane ; Tris(methoxyethxy)vinylsilane ; Vinyltris(2-methoxyethoxy)silane ; Vinyltris(methoxyethoxy)silane ; Z 6030 ; 2,5,7,10-Tetraoxa-6-silaundecane, 6-ethenyl-6-(2-methoxyethoxy)- ; 6-Ethenyl-6-(methoxyethoxy)-2,5,7,10-tetraoxa-6-silaundecane (9CI) ; Silane, tris(2-methoxyethoxy)vinyl-
CAS NO: 1067-53-4
Classification Code: Skin / Eye Irritant
Melting point: -30 °C
Polar Surface Area: 55.38 Å²
Index of Refraction: 1.428
Molar Refractivity: 71.92 cm³
Molar Volume: 279.1 cm³
Surface Tension: 26.9 dyne/cm
Density: 1.004 g/cm³
Flash Point: 104.8 °C
Enthalpy of Vaporization: 50.76 kJ/mol
Boiling Point: 289.5 °C at 760 mmHg
Vapour Pressure: 0.00381 mmHg at 25°C

Uses

Tris(methoxyethoxy)vinylsilane (CAS NO.1067-53-4) is used as modifiers of polymer materials, EPDM rubber modifier, silane cross-linking agent of cross-linked cable, glass fiber treatment agent, also used in the manufacture of hydrophobic agents.

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rabbit	LD50	skin	1500uL/kg (1.5mL/kg)		Union Carbide Data Sheet. Vol. 1/30/1964,
rat	LD50	oral	2960mg/kg (2960mg/kg)		Union Carbide Data Sheet. Vol. 1/30/1964,

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Safety Information of Tris(methoxyethoxy)vinylsilane (CAS NO.1067-53-4):
Hazard Codes:Xn ,T
Risk Statements: 36-62-61-20/21/22
R36: Irritating to eyes.
R62: Risk of impaired fertility.
R61: May cause harm to the unborn child.
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
Safety Statements: 26-53-45-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S53: Avoid exposure - obtain special instructions before use.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 1993
WGK Germany: 1
RTECS: VV6826000
TSCA: Yes
HazardClass: 3.2
PackingGroup: III
Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

Specification

First Aid Measures of Tris(methoxyethoxy)vinylsilane (CAS NO.1067-53-4):
Eyes:Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:Get medical aid. Wash mouth out with water.
Inhalation:Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Storage of Tris(methoxyethoxy)vinylsilane (CAS NO.1067-53-4):
Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container.