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112-26-5

Basic Information
CAS No.: 112-26-5
Name: 1,2-Bis(2-chloroethoxy)ethane
Article Data: 33
Cas Database
Molecular Structure:
Molecular Structure of 112-26-5 (1,2-Bis(2-chloroethoxy)ethane)
Formula: C6H12Cl2O2
Molecular Weight: 187.066
Synonyms: 1,2-Bis(chloroethoxy)ethane;1,8-Dichloro-3,6-dioxaoctane;Bis(2-chloroethoxy)ethane;Bis(chloroethoxy)ethane;Ethylene glycolbis(2-chloroethyl) ether;Triethylene glycol dichloride;Triglycol dichloride;
EINECS: 203-952-7
Density: 1.147 g/cm3
Melting Point: -31°C
Boiling Point: 230 °C at 760 mmHg
Flash Point: 121.1 °C
Solubility: Insoluble in water
Appearance: clear colorless to pale yellow liquid
Hazard Symbols: HarmfulXn
Risk Codes: 19-21/22-37/38-41-36/37/38
Safety: 26-36/37/39
Transport Information: UN 2810 6.1/PG 3
PSA: 18.46000
LogP: 1.49720
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    Product Name: 1,2-Bis(2-chloroethoxy)ethane CAS: 112-26-5 MF: C6H12Cl2O2 MW: 187.06 EINECS: 203-952-7 Mol File: 112-26-5.mol 1,2-Bis(2-chloroethoxy)ethane Structure 1,2-Bis(2-chloroethoxy)ethane Chemical Properties Melting point

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Chemistry

 Triglycol dichloride (112-26-5) is called for 1,2-Bis(2-chloroethoxy)ethane ;  1,2-Bis(chlorethoxy)ethane ; 2-(2-Chloroethoxy)ethyl 2'-chloroethyl ether ; Dichlorotriethylene dioxide ; Ethane, 1,2-bis(2-chloroethoxy)- ; 1,8-Dichloro-3,6-dioxaoctane ; HSDB 5400 ,and so on. Triglycol dichloride (112-26-5) is clear colorless to pale yellow liquid.

IUPAC Name: 1,2-Bis(2-chloroethoxy)ethane
CAS: 112-26-5
Molecular Formula: C6H12Cl2O2
Molecular Weight: 187.06
Molecular structure:
EINECS: 203-952-7
Melting point:  -31°C
Water Solubility:  insoluble
BRN:  506177
ACD/LogD (pH 5.5): 0.83 
ACD/LogD (pH 7.4): 0.83 
ACD/BCF (pH 5.5): 2.51 
ACD/BCF (pH 7.4): 2.51 
ACD/KOC (pH 5.5): 67.24 
ACD/KOC (pH 7.4): 67.24 
H bond acceptors: 2 
H bond donors: 0 
Freely Rotating Bonds: 7 
Index of Refraction: 1.44 
Molar Refractivity: 43.03 cm3 
Molar Volume: 163 cm3 
Polarizability: 17.06 10-24cm3 
Surface Tension: 31.7 dyne/cm 
Density: 1.147 g/cm
Flash Point: 121.1 °C 
Enthalpy of Vaporization: 44.77 kJ/mol 
Boiling Point: 230 °C at 760 mmHg 
Vapour Pressure: 0.102 mmHg at 25°C 

Uses

1. Triglycol dichloride (112-26-5) is comonly used as solvent for hydrocarbons, oils, etc. 2. Triglycol dichloride (112-26-5) can be used as extractant, intermediate for resins, insecticides, and organic synthesis.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 oral 120mg/kg (120mg/kg) BEHAVIORAL: GENERAL ANESTHETIC

GASTROINTESTINAL: OTHER CHANGES

KIDNEY, URETER, AND BLADDER: OTHER CHANGES
Journal of Industrial Hygiene and Toxicology. Vol. 23, Pg. 259, 1941.
rabbit LD50 skin 1410uL/kg (1.41mL/kg)   Union Carbide Data Sheet. Vol. 8/28/1957,
rat LD50 oral 250mg/kg (250mg/kg)   Union Carbide Data Sheet. Vol. 8/28/1957,

RTECS:  KH4900000

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion. Moderately toxic by skin contact. A skin and eye irritant. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl.
Hazard Codes:  Xn
Risk Statements:  19-21/22-37/38-41-36/37/38 (19:  May form explosive peroxides 21/22:  Harmful in contact with skin and if swallowed 37/38:  Irritating to respiratory system and skin 41:  Risk of serious damage to eyes 36/37/38:  Irritating to eyes, respiratory system and skin)
Safety Statements:  26-36/37/39 (26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 36/37/39:  Wear suitable protective clothing, gloves and eye/face protection)
RIDADR:  UN 2810 6.1/PG 3
WGK Germany:  3
HazardClass:  6.1
PackingGroup:  III
HS Code:  29091900

Specification

Removal in wastewater treatment of Triglycol dichloride (112-26-5) can be stated as follows:
Total removal:1.97  percent
Total biodegradation:0.09  percent
Total sludge adsorption:1.83  percent
Total to Air:0.04  percent
(using 10000 hr Bio P,A,S)

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