Products Categories
| CAS No.: | 13453-69-5 |
|---|---|
| Name: | Boric acid (HBO2),lithium salt (1:1) |
| Article Data: | 7 |
| Cas Database | |
| Molecular Structure: | |
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| Formula: | LiBO2 |
| Molecular Weight: | 49.7508 |
| Synonyms: | lithium,oxido(oxo)borane;Boric acid lithium salt;Lithium metaborate; |
| EINECS: | 236-631-5 |
| Density: | 1.4 g/cm3 |
| Melting Point: | 845 °C(lit.) |
| Boiling Point: | N/A |
| Flash Point: | N/A |
| Solubility: | N/A |
| Appearance: | white powder |
| Hazard Symbols: | N/A |
| Risk Codes: | 20/21/22-41 |
| Safety: | 24/25 |
| Transport Information: | N/A |
| PSA: | 40.13000 |
| LogP: | -0.88610 |
| Conditions | Yield |
|---|---|
| thermal decompn. in air at 115°C and in N2 atmosphere at 120°C; |
A
lithium metaborate
B
water
| Conditions | Yield |
|---|---|
| With oxygen byproducts: CO2; oxisative decompn. on heating; | |
| With O2 byproducts: CO2; oxisative decompn. on heating; |
| Conditions | Yield |
|---|---|
| In neat (no solvent, solid phase) heating in air (800°C); |
| Conditions | Yield |
|---|---|
| With cobalt(II) chloride at 20℃; |
| Conditions | Yield |
|---|---|
| In water at 20℃; for 1h; Schlenk technique; Inert atmosphere; Sonication; |
| Conditions | Yield |
|---|---|
| In methanol with exclusion of air in excess anhydrous methanol; between room temp. and boiling; by refluxing; | |
| In methanol with exclusion of air in excess anhydrous methanol; between room temp. and boiling; by refluxing; |
| Conditions | Yield |
|---|---|
| In water in concd.soln.; pptd. with alcohol; | |
| In water in concd.soln.; pptd. with alcohol; |
| Conditions | Yield |
|---|---|
| with anhydrous CH3OH; reflux; exclusion of air; addn. of dimethyl ether to filtrate; drying at room temp.; | |
| with anhydrous CH3OH; reflux; exclusion of air; addn. of dimethyl ether to filtrate; drying at room temp.; |
| Conditions | Yield |
|---|---|
| In neat (no solvent) melting, cooling from 1198 K to 698 K (6 K/h); washing (hot distd. water); |
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The Lithium metaborate, also known as Lithium Tetraborate, is an chemical compound with the formula LiBO2. It belongs to the product categories of Inorganics; ACS Grade Synthetic Reagents; Essential Chemicals; Inorganic Salts; Lithium; Routine Reagents; Lithium Salts; Metal and Ceramic Science; Salts. Its EINECS registry number is 236-631-5. With the CAS registry number 13453-69-5, its IUPAC name is lithium oxido(oxo)borane.
Physical properties of Lithium metaborate: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 2; (3)Rotatable Bond Count: 0; (4)Exact Mass: 50.015139; (5)MonoIsotopic Mass: 50.015139; (6)Topological Polar Surface Area: 40.1; (7)Heavy Atom Count: 4; (8)Formal Charge: 0; (9)Complexity: 13.5; (10)Isotope Atom Count: 0; (11)Defined Atom StereoCenter Count: 0; (12)Undefined Atom StereoCenter Count: 0; (13)Defined Bond StereoCenter Count: 0; (14)Undefined Bond StereoCenter Count: 0; (15)Covalently-Bonded Unit Count: 2.
Preparation of Lithium metaborate: This chemical can be prepared by fused lithium hydroxide or lithium carbonate and boric acid in right chemistry proportion.
B2O + Li2CO3 = 2LiBO2 + CO2
Uses of Lithium metaborate: It can be used in borate fusion sample preparation of various samples for analysis by XRF, AAS, ICP-OES, ICP-AES and ICP-MS.
When you are using this chemical, please be cautious about it as the following:
This chemical is harmful by inhalation, in contact with skin and if swallowed. In addition, there will be a risk of serious damage to eyes. When using it, you must avoid contact with skin and eyes.
You can still convert the following datas into molecular structure:
(1)Canonical SMILES: [Li+].B(=O)[O-]
(2)InChI: InChI=1S/BO2.Li/c2-1-3;/q-1;+1
(3)InChIKey: HZRMTWQRDMYLNW-UHFFFAOYSA-N
