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142-16-5

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Basic Information
CAS No.: 142-16-5
Name: 2-Butenedioic acid(2Z)-, 1,4-bis(2-ethylhexyl) ester
Article Data: 9
Cas Database
Molecular Structure:
Molecular Structure of 142-16-5 (2-Butenedioic acid(2Z)-, 1,4-bis(2-ethylhexyl) ester)
Formula: C20H36O4
Molecular Weight: 340.503
Synonyms: 2-Butenedioic acid (Z)-,bis(2-ethylhexyl) ester;Maleic acid, bis(2-ethylhexyl) ester (6CI,7CI,8CI);Bis(2-ethylhexyl) maleate;Ceraphyl 45;Di-2-ethylhexyl maleate;Dioctylmaleate;2-Butenedioicacid (2Z)-, bis(2-ethylhexyl) ester (9CI);
EINECS: 205-524-5
Density: 0.945 g/cm3
Melting Point: -50°C
Boiling Point: 409.8 °C at 760 mmHg
Flash Point: 190.4 °C
Solubility: N/A
Appearance: Clear to yellow liquid
Hazard Symbols: IrritantXi
Risk Codes: 36/38
Safety: 26-36
Transport Information: N/A
PSA: 52.60000
LogP: 5.06180
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ConditionsYield
With 3,3′-(2,2-bis(hydroxymethyl)propane-1,3-diyl)bis(1-methyl-1H-imidazol-3-ium) hydrogen sulfate for 2h; Dean-Stark; Reflux;100%
Bei an einer mit einem Trockenmittel gefuellten Kolonne;
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Conditions
ConditionsYield
With sulfuric acid; 2,6-di-tert-butyl-4-hydroxytoluene In benzene at 90℃; for 2.5h; Heating / reflux;90%
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maleic acid

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bis(2-ethylhexyl) maleate

"1,4-bis(2-ethylhexyl) but-2-ynedioate

A

142-16-5

bis(2-ethylhexyl) maleate

B

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bis(2-ethylhexyl) (2E)-2-butenedioate

Conditions
ConditionsYield
With TPPMS (meta-monosulfonated triphenylphosphane, Na salt); water for 24h;
109-99-9

tetrahydrofuran

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bis(2-ethylhexyl) maleate

2-(tetrahydro-2-furanyl) butanedioic acid 1,4-bis(2-ethylhexyl) ester

2-(tetrahydro-2-furanyl) butanedioic acid 1,4-bis(2-ethylhexyl) ester

Conditions
ConditionsYield
With di-tert-butyl peroxide at 20℃; for 4h; UV-irradiation; Inert atmosphere; Overall yield = 96 percent; diastereoselective reaction;A 59%
B 29%
...Expand
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DL-thiomalic acid

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bis(2-ethylhexyl) maleate

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sodium 3-<<1,2-bis<<(2-ethylhexyl)oxy>carbonyl>ethyl>thio>succinate

Conditions
ConditionsYield
With sodium hydroxide In water; N,N-dimethyl-formamide50%
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bis(2-ethylhexyl) maleate

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ethylenediamine

[S,S]-[R,R]-[R,S]-ethylenediaminedisuccinic acid tetraisooctyl ester

Conditions
ConditionsYield
In toluene at 20 - 80℃; for 4h; Heating / reflux;30%
142-16-5

bis(2-ethylhexyl) maleate

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bis(2-ethylhexyl) sulfosuccinate

Conditions
ConditionsYield
With water; sodium hydrogensulfite at 100℃;
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With ethanol; water; sodium hydrogensulfite at 100℃;
With water; sodium hydrogensulfite at 100℃;
142-16-5

bis(2-ethylhexyl) maleate

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Conditions
ConditionsYield
With hydrogen sulfide; triethylamine at 50℃;
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142-16-5

bis(2-ethylhexyl) maleate

123-72-8

butyraldehyde

butyryl-succinic acid bis-(2-ethyl-hexyl ester)

Conditions
ConditionsYield
With dibenzoyl peroxide
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Chemistry

Molecular structure:


MF: C20H36O4
MW: 340.5
EINECS: 220-835-6
Product Categories: Fatty Acid Esters (Plasticizer);Functional Materials;Plasticizer;Plasticizers;Polymer Additives;Polymer Science
Mol File: 142-16-5.mol 
refractive index : n20/D 1.455(lit.)
Fp : >230 °F
BIS(2-ETHYLHEXYL) MALEATE's mp is -50°C, bp is 208-209°C (10mmHg), and density is 0.944 g/mL at 25 °C(lit.). 

Uses

BIS(2-ETHYLHEXYL) MALEATE is used in copolymers, intermediate prc- in chemical reactions.

Safety Profile

Hazard Codes : Xi
Risk Statements : 36/38
Safety Statements : 26-36
WGK Germany : 1
RTECS : ON0160000
Hazardous Substances Data :142-16-5(Hazardous Substances Data)