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142-83-6

Basic Information
CAS No.: 142-83-6
Name: 2,4-Hexadienal,(2E,4E)-
Article Data: 50
Cas Database
Molecular Structure:
Molecular Structure of 142-83-6 (2,4-Hexadienal,(2E,4E)-)
Formula: C6H8O
Molecular Weight: 96.1289
Synonyms: 2,4-Hexadienal,(E,E)-;Sorbaldehyde (6CI,7CI,8CI);(2E,4E)-2,4-Hexadienal;(E,E)-Hexa-2,4-dienal;Sorbic aldehyde;trans-2,trans-4-Hexadienal;
EINECS: 205-564-3
Density: 0.857 g/cm3
Melting Point: -16.5°C
Boiling Point: 155.858 °C at 760 mmHg
Flash Point: 67.778 °C
Solubility: It is Insoluble in water, but soluble in ethanol.
Appearance: liquid
Hazard Symbols: ToxicT
Risk Codes: 22-24-34-43
Safety: 26-36/37/39-45
Transport Information: UN 2922 8/PG 3
PSA: 17.07000
LogP: 1.31760
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Chemistry

UPAC Name:(2E,4E)-Hexa-2,4-dienal
Synonyms : Trans,Trans-2,4-Hexadienal
Molecular Structure:
Molecular Formula: C6H8O
Molecular Weight : 96.13
CAS NO: 142-83-6
EINECS : 205-564-3
FEMA : 3429
BRN : 1698401
Density : 0.871
Boiling point: 170-173 ºC
Refractive index : 1.541
Flash point : 68 ºC
Index of Refraction: 1.45
Surface Tension: 26.4 dyne/cm
Enthalpy of Vaporization: 39.26 kJ/mol
Vapour Pressure: 2.97 mmHg at 25°C
Storage temp: 2-8°C
Appearance: liquid
Sensitive: Air Sensitive
Stability: Sorbaldehyde (CAS NO. 142-83-6)  is stable, combustible. Incompatible with strong reducing agents, strong bases, strong oxidizing agents.

Toxicity Data With Reference

1.    

skn-rbt 10 mg/24H SEV

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
2.    

eye-rbt 750 µg SEV

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
3.    

mmo-sat 500 nmol/L

    MUREAV    Mutation Research. 148 (1985),25.
4.    

orl-rat LD50:300 mg/kg

    FCTOD7    Food and Chemical Toxicology. 26 (1988),337.
5.    

ihl-rat LCLo:2000 ppm/4H

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
6.    

skn-gpg LDLo:2500 mg/kg

    FCTOD7    Food and Chemical Toxicology. 26 (1988),337.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes  T,Xi,Xn
Risk Statements  24-34-43-36/37/38-20/21/22
24:  Toxic in contact with skin 
34: Sorbaldehyde (CAS NO. 142-83-6)  causes burns 
43:  May cause sensitization by skin contact 
20/21/22:  Harmful by inhalation, in contact with skin and if swallowed
36/37/38:  Irritating to eyes, respiratory system and skin  
Safety Statements  26-36/37/39-45-36
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36:  Wear suitable protective clothing 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection 
RIDADR  UN 2922 8/PG 3
WGK Germany  3
RTECS  WG1925000
F  1-10
Hazard Note  Irritant
HazardClass  6.1
PackingGroup  III

Specification

1.General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire.
2.Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. 
3.Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
4.Storage: Keep Sorbaldehyde (CAS NO. 142-83-6) away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket. Keep refrigerated. (Store below 4°C/39°F.)