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| CAS No.: | 156-60-5 |
|---|---|
| Name: | trans-1,2-Dichloroethylene |
| Article Data: | 79 |
| Cas Database | |
| Molecular Structure: | |
|
|
|
| Formula: | C2H2Cl2 |
| Molecular Weight: | 96.9439 |
| Synonyms: | Ethene,1,2-dichloro-, (E)-;Ethylene, 1,2-dichloro-, (E)- (8CI);Ethylene,1,2-dichloro-, trans- (5CI);(E)-1,2-Dichloroethene;(E)-1,2-Dichloroethylene;1,2-trans-Dichloroethene;Ethene, 1,2-dichloro-,(1E)-;HCC 1130t;NSC 60512;R1130t;trans-1,2-Dichloroethene; |
| EINECS: | 205-860-2 |
| Density: | 1.243 g/cm3 |
| Melting Point: | ?57 °C(lit.) |
| Boiling Point: | 47.7 °C at 760 mmHg |
| Flash Point: | 6.1 °C |
| Solubility: | Insoluble in water |
| Appearance: | Clear liquid |
| Hazard Symbols: |
 Xn,  F,  T
|
| Risk Codes: | 11-20-52/53-39/23/24/25-23/24/25 |
| Safety: | 7-16-29-61-45-36/37 |
| Transport Information: | UN 1150 3/PG 2 |
| PSA: | 0.00000 |
| LogP: | 1.93520 |
| Conditions | Yield |
|---|---|
| 100% | |
| 50% |
1,1,2,2-tetrachloroethylene
A
cis-1,2-Dichloroethylene
B
trans-1,2-dichloroethylene
C
Trichloroethylene
| Conditions | Yield |
|---|---|
| With methanol at 20℃; Inert atmosphere; UV-irradiation; | A n/a B n/a C 43% |
| With Desulfomonile tiedjei DCB-1 In water at 35℃; Kinetics; Further Variations:; Reagents; time; concentration; Dehalogenation; |
| Conditions | Yield |
|---|---|
| at 100 - 250℃; Gleichgewicht der photochemischen Isomerisierung in der Gasphase im UV-Licht; | |
| at 300℃; Gleichgewicht der thermischen Isomerisierung; | |
| at 350℃; Gleichgewicht der thermischen Isomerisierung; |
| Conditions | Yield |
|---|---|
| With oxygen; chlorine; copper(II) oxide at 375 - 425℃; |
| Conditions | Yield |
|---|---|
| With copper chloride +pumice stone at 400 - 450℃; | |
| With copper chloride; pumice stone at 400 - 450℃; |
1,1,2-trichloroethane
A
cis-1,2-Dichloroethylene
B
trans-1,2-dichloroethylene
C
1,1-Dichloroethylene
| Conditions | Yield |
|---|---|
| at 500℃; bei der thermischen Zersetzung; | |
| at 500℃; Geschwindigkeit dieser Spaltung bei verschiedenen Temperaturen und Beschleunigung der Pyrolyse durch geringe Mengen Sauerstoff oder Chlor; |
| Conditions | Yield |
|---|---|
| With chlorine In solid at -213.1℃; Product distribution; Quantum yield; Mechanism; Irradiation; various temperatures; | |
| With antimonypentachloride | |
| With nitrosylchloride at 350℃; |
| Conditions | Yield |
|---|---|
| With aqueous CuCl2+CuCl+NH4Cl at 50 - 85℃; | |
| With iron(III) chloride; ammonium chloride; copper(l) chloride at 50 - 85℃; | |
| With hydrogenchloride; water; copper(l) chloride at 80 - 110℃; |
| Conditions | Yield |
|---|---|
| With chlorine; pyrographite at 40℃; | |
| With chlorine; copper dichloride at 200 - 240℃; |
1,1,2,2-tetrachloroethane
A
cis-1,2-Dichloroethylene
B
trans-1,2-dichloroethylene
| Conditions | Yield |
|---|---|
| With sodium amalgam; water | |
| With hydrogen; copper at 370 - 440℃; | |
| With zinc In ethanol |
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IUPAC Name: (E)-1,2-Dichloroethene
Molecular Weight: 96.94328 g/mol
Molecular Formula: C2H2Cl2
Density: 1.243 g/cm3
Melting Point: −57 °C(lit.)
Boiling Point: 47.7 °C at 760 mmHg
Flash Point: 6.1 °C
Index of Refraction: 1.453
Molar Refractivity: 21.07 cm3
Molar Volume: 77.9 cm3
Surface Tension: 25.9 dyne/cm
Enthalpy of Vaporization: 27.93 kJ/mol
Vapour Pressure: 333 mmHg at 25 °C
Exact Mass: 95.953355
EINECS: 205-860-2
Properties: colourless liquid
Product categories: Organics ; Analytical Chemistry ; Standard Solution of Volatile Organic Compounds for Water , Soil Analysis ; Standard Solutions (VOC) ; Alpha Sort ; D ; DAlphabetic ; DIA - DIC ; Volatiles/ Semivolatiles
Mmolecular structure of trans-1,2-Dichloroethylene (CAS NO.156-60-5):
| 1. | skn-rbt 500 mg/24H MOD | JACTDZ Journal of the American College of Toxicology. 1 (1990),11. | ||
| 2. | eye-rbt 10 mg MOD | JACTDZ Journal of the American College of Toxicology. 1 (1990),11. | ||
| 3. | mma-smc 80 mmol/L | TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis. 4 (1984),365. | ||
| 4. | ihl-rat TCLo:12,000 ppm/6H (female 7-16D post):REP | FAATDF Fundamental and Applied Toxicology. 20 (1993),225. | ||
| 5. | ihl-hmn TCLo:4800 mg/m3/10M:CNS | AHBAAM Archiv fuer Hygiene und Bakteriologie. 116 (1936),131. | ||
| 6. | orl-rat LD50:1235 mg/kg | TXCYAC Toxicology. 7 (1977),141. | ||
| 7. | ipr-rat LD50:7411 mg/kg | TXCYAC Toxicology. 7 (1977),141. | ||
| 8. | orl-mus LD50:2122 mg/kg | DCTODJ Drug and Chemical Toxicology. 8 (1985),373. | ||
| 9. | ipr-rat LD50:7536 mg/kg | TXCYAC Toxicology. 7 (2)(1977),141. | ||
| 10. | ihl-mus LCLo:75,000 mg/m3/2H | AHBAAM Archiv fuer Hygiene und Bakteriologie. 116 (1936),131. | ||
| 11. |
|
Reported in EPA TSCA Inventory.
Moderately toxic by ingestion. Mildly toxic by inhalation. Human systemic effects by inhalation: sleep, hallucinations, and distorted perceptions. Experimental reproductive effects. A skin and eye irritant. Mutation data reported. Exposure to high vapor concentration can cause nausea, vomiting, weakness, tremor, and cramps. Recovery is usually prompt following removal from exposure. Dermatitis may result from defatting action on skin. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderate explosion hazard in the form of vapor when exposed to flame. Violent reaction with difluoromethylene dihypofluorite. Forms shock-sensitive explosive mixtures with dinitrogen tetraoxide. Reaction with solid caustic alkalies or their concentrated solutions produces chloracetylene gas that ignites spontaneously in air. Reacts violently with N2O4, KOH, Na, NaOH. Moderate explosion hazard in the form of vapor when exposed to flame. Can react vigorously with oxidizing materials. To fight fire, use water spray, foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORIDES; CHLORINATED HYDROCARBONS, ALIPHATIC; and ACETYLENE COMPOUNDS and ALKYNES.
Hazard Codes: 
F, 
Xn, 
T
Risk Statements: 11-20-52/53-39/23/24/25-23/24/25
R11: Highly flammable.
R20: Harmful by inhalation.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R39: Danger of very serious irreversible effects.
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
Safety Statements: 7-16-29-61-45-36/37
S7: Keep container tightly closed.
S16: Keep away from sources of ignition.
S29: Do not empty into drains.
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37: Wear suitable protective clothing and gloves.
RIDADR: UN 1150 3/PG 2
WGK Germany: 2
RTECS: KV9400000
HazardClass: 3
PackingGroup: II
DFG MAK: 200 ppm (800 mg/m3)
The chemical synonyms of trans-1,2-Dichloroethylene (CAS NO.156-60-5) are (E)-1,2-Dichloroethene ; (E)-1,2-Dichloroethylene ; 4-01-00-00709 (Beilstein Handbook Reference) ; AI3-28786 ; BRN 1420761 ; CCRIS 2505 ; Ethylene, 1,2-dichloro-, trans- ; HCC 1130t ; HSDB 6361 ; NSC 60512 ; R 1130t ; RCRA waste number U079 ; trans-Acetylene dichloride ; trans-Dichloroethylene . It is highly flammable. Oxidizes in air to form unstable peroxides that may explode spontaneously. Avoid contact with copper and copper alloys. trans-1,2-Dichloroethylene reacts with alkalis, difluoromethylene, dihypofluorite, and nitrogen tetraoxide. Contact with solid alkalis or their concentrated solutions will cause formation of chloroacetylene, which ignites in air. Corrosive to metals unless an inhibitor has been added. Oxidation in the presence of concentrated sulfuric acid or a free radical initiator gives chloroacetyl chloride via epoxide intermediates. It is incompatible with organic peroxides.
