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| CAS No.: | 2451-62-9 |
|---|---|
| Name: | 1,3,5-Triglycidyl isocyanurate |
| Molecular Structure: | |
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| Formula: | C12H15 N3 O6 |
| Molecular Weight: | 297.268 |
| Synonyms: | 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione,1,3,5-tris(oxiranylmethyl)- (9CI);s-Triazine-2,4,6(1H,3H,5H)-trione,tris(2,3-epoxypropyl)- (7CI);1,3,5-Triglycidyl-s-triazine-2,4,6-trione;1,3,5-Tris(oxiranylmethyl)-1,3,5-triazine-2,4,6-trione;N,N',N''-Triglycidyl isocyanurate;NSC 269934;TGT;Triglycidylisocyanurate; |
| EINECS: | 219-514-3 |
| Density: | 1.625 g/cm3 |
| Melting Point: | 95-98 °C |
| Boiling Point: | 501.1 °C at 760 mmHg |
| Flash Point: | 256.9 °C |
| Solubility: | water: <0.1 g/100 mL at 20 °C |
| Appearance: | white crystalline solid |
| Hazard Symbols: |
 T
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| Risk Codes: | 46-23/25-41-43-48/22-52/53 |
| Safety: | 53-45-61 |
| Transport Information: | UN 2811 6.1/PG 3 |
| PSA: | 103.59000 |
| LogP: | -2.63190 |
| Conditions | Yield |
|---|---|
| With dihydrogen peroxide; benzyl bromide In dimethyl sulfoxide at 20 - 70℃; for 4h; Reagent/catalyst; Solvent; Temperature; | 85% |
| Conditions | Yield |
|---|---|
| Stage #1: cyanuric acid With sodium hydroxide at 60℃; pH=7.5; Stage #2: epichlorohydrin With benzyltrimethylammonium chloride at 115 - 120℃; for 7.5h; Catalytic behavior; Temperature; | 84% |
| Stage #1: cyanuric acid; epichlorohydrin With benzyltrimethylammonium chloride In water Autoclave; Heating; Stage #2: With sodium hydroxide In dichloromethane | 67% |
| Conditions | Yield |
|---|---|
| With sodium phosphate dodecahydrate; dihydrogen peroxide; sodium hydrogencarbonate; sodium carbonate In methanol; water; acetonitrile at 20℃; for 15h; pH=10.6; |
| Conditions | Yield |
|---|---|
| With sodium hydroxide In methanol at 15℃; for 1.5h; Temperature; Solvent; Large scale; | |
| With potassium hydroxide In water at 35 - 50℃; for 4h; Temperature; Reagent/catalyst; |
| Conditions | Yield |
|---|---|
| Stage #1: isocyanuric acid; epichlorohydrin With N-benzyl-N,N,N-triethylammonium chloride at 80℃; Stage #2: With sodium hydroxide at 15℃; for 1h; Temperature; |
| Conditions | Yield |
|---|---|
| With sodium hydroxide In water at 55 - 80℃; for 5h; Reagent/catalyst; Temperature; |
| Conditions | Yield |
|---|---|
| In methanol; 1,2-dimethoxyethane at 25℃; for 51h; | 100% |
| Conditions | Yield |
|---|---|
| Stage #1: Mono(2-methacryloyloxy)ethylphthalate; teroxirone With triphenylantimony at 100℃; for 5h; Stage #2: With triphenylphosphine at 100℃; for 3h; | 100% |
| Conditions | Yield |
|---|---|
| In methanol for 24h; Heating / reflux; | 98.6% |
| In methanol at 60℃; for 24h; | 96.6% |
4-AMINO-2,2,6,6-TETRAMETHYLPIPERIDINE
teroxirone
tris[2-hydroxy-3-(2,2,6,6-tetramethyl-4-piperidylamino)propyl] isocyanurate
| Conditions | Yield |
|---|---|
| 97.4% |
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The triglycidyl isocyanurate , with the register number 2451-62-9, has other names as 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione,1,3,5-tris(oxiranylmethyl)-;1,3,5-triglycidylisocyanuricacid;1,3,5-triglycidyl-s-triazinetrione;1,3,5-truglycidyl-s-triazinetrione;3,5-Triazine-2,4,6(1H,3H,5H)-trione,1,3,5-tris(oxiranylmethyl)-1;5-triazine-2,4,6(1h,3h,5h)-trione,1,3,5-tris(oxiranemethyl)-3;5-triazine-2,4,6(1h,3h,5h)-trione,1,3,5-tris(oxiranylmethyl)-3;6(1h,3h,5h)-trione,1,3,5-tris(2,3-epoxypropyl)-s-triazine-4 .
The physical properties of this kind of chemical are as following: (1)#H bond acceptors: 9 ; (2)#Freely Rotating Bonds: 6 ; (3)Polar Surface Area: 98.52 ; (4)Index of Refraction: 1.635 ; (5)Molar Refractivity: 65.48 cm3 ; (6)Molar Volume: 182.8 cm3 ; (7)Polarizability: 25.96 ×10-24 cm3 ; (8)Surface Tension: 77.2 dyne/cm ; (9)Density: 1.625 g/cm3 ; (10)Flash Point: 256.9 °C ; (11)Enthalpy of Vaporization: 76.99 kJ/mol ; (12)Boiling Point: 501.1 °C at 760 mmHg ; (13)Vapour Pressure: 3.56E-10 mmHg at 25°C.
It is a kind of white crystalline and its water dissolubility information is <0.1 g/100 mL at 20 ºC. As for its usage, it is widely usde in many fields, such as being the curing agent of the polyester powder and also could be used in making Electrical insulating materials, printed circuit, adhesive and stabilizer for plastics. What's more, its product categories are including oxiranes;simple 3-Membered ring compounds.
Being a kind of toxic chemical, it may cause many damages in many ways: At low levels, it cause damage to health; It may cause heritable genetic damage; Toxic by inhalation and if swallowed; Risk of serious damage to eyes; May cause sensitisation by skin contact; Danger of serious damage to health by prolonged exposure. Besides, it is very harmful to aquatic organisms, may cause long-term adverse. effects in the aquatic environment.
As for so many impossible damages, you should be very cautious while dealing with this kind of chemical: Avoid exposure - obtain special instructions before use and in case of accident or if you feel unwell seek medical advice immediately (show the label where possible). Besides, avoid release to the environment. Refer to special instructions/safety data sheet. You could also get more safety information of WGK Germany 3.
In addition, you could refer to the following data information to get the molecular structure:
SMILES:O=C1N(C(=O)N(C(=O)N1CC2OC2)CC3OC3)CC4OC4
InChI:InChI=1/C12H15N3O6/c16-10-13(1-7-4-19-7)11(17)15(3-9-6-21-9)12(18)14(10)2-8-5-20-8/h7-9H,1-6H2
InChIKey:OUPZKGBUJRBPGC-UHFFFAOYAU
Below are the toxicity information of this kind of chemcial:
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| rat | LD50 | oral | 188mg/kg (188mg/kg) | LUNGS, THORAX, OR RESPIRATION: DYSPNEA GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" SKIN AND APPENDAGES (SKIN): HAIR: OTHER | National Technical Information Service. Vol. OTS0555027, |
