CAS No.5144-89-8,1,10-Phenanthroline hydrate Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	5144-89-8
Name:	1,10-Phenanthroline hydrate

Formula:	C₁₂H₈N₂^.H₂O
Molecular Weight:	198.224
Synonyms:	4,5-Phenanthroline monohydrate;1,10-Phenanthroline Monohydrate;o-Phenanthroline monohydrate;1,10-Phenanthroline 1-hydrate;1,10-Phenanthroline GR monohydrate;1,10-Phenanthroline AR;
EINECS:	200-629-2
Density:	1.10
Melting Point:	100-104 °C(lit.)
Boiling Point:	365.1 °C at 760 mmHg
Flash Point:	164.8 °C
Solubility:	<0.01 g/100 mL at 21 °C
Appearance:	white crystals or powder
Hazard Symbols:	T, N
Risk Codes:	25-50/53
Safety:	45-60-61
Transport Information:	UN 2811
PSA:	35.01000
LogP:	2.71870

Synthetic route

: 6156-78-1
manganese (II) acetate tetrahydrate

: 5144-89-8
1,10-phenanthroline hydrate

: {Mn3(O2CCH3)6(1,10-phenanthroline)2}

Conditions

Conditions	Yield
In N,N-dimethyl-formamide stirred for 10 min; filtered, washed with DMF, acetone and diethyl ether, dried in vac.; elem. anal.;	99%

: tetrakis(acetonitrile)copper(I)tetrafluoroborate

: 5144-89-8
1,10-phenanthroline hydrate

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 498584-34-2
(1,10-phenanthroline)(1,2-bis(diphenylphosphino)ethane)copper(I) tetrafluoroborate

Conditions

Conditions	Yield
In dichloromethane (N2); Cu complex was reacted with P ligand in CH2Cl2; phenanthroline wasadded after dissolution; mixt. was stirred for 1 h; solvent removed (vac.); Et2O added; pptd.; washed (Et2O);	99%

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: 7647-01-0
hydrogenchloride

: sodium tetrachloropalladate(II)

: 5144-89-8
1,10-phenanthroline hydrate

: 14783-10-9
[palladium(II)dichloride(1,10-phenanthroline)]

Conditions

Conditions	Yield
In water stirring Na2PdCl4 with 1 equiv. ligand and excess HCl (80°C, 30 min); standing at room temp. for several h, collection (filtration), washing (water, MeOH); elem. anal.;	99%

...Expand

: 5144-89-8
1,10-phenanthroline hydrate

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: copper(II) nitrate

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 498584-36-4
[Cu(1,2-bis(diphenylphosphino)ethane)(1,10-phenanthroline)]NO3

Conditions

Conditions	Yield
In acetonitrile (N2); mixt. of Cu(NO3)2 and Cu in CH3CN was stirred for 2 h; filtered under N2; P ligand and phenanthroline were subsequently added to filtrate;soln. was stirred for 15 min; solvent removed (vac.); extd. (CH2Cl2); CH2Cl2 removed (vac.); Et2O added; washed (Et2O);	99%

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: 14057-91-1
tetrakis(acetonitrile)copper(I) perchlorate

: 5144-89-8
1,10-phenanthroline hydrate

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 498584-33-1
[Cu(1,2-bis(diphenylphosphino)ethane)(1,10-phenanthroline)]ClO4

Conditions

Conditions	Yield
In dichloromethane (N2); Cu complex was reacted with P ligand in CH2Cl2; phenanthroline wasadded after dissolution; mixt. was stirred for 1 h; solvent removed (vac.); Et2O added; pptd.; washed (Et2O);	99%

...Expand

: 5144-89-8
1,10-phenanthroline hydrate

: 65115-91-5
5,6-epoxy-5,6-dihydro-[1,10]phenanthroline

Conditions

Conditions	Yield
With industrial bleach (pH 8.2-8.3 with conc. HCl); tetra(n-butyl)ammonium hydrogensulfate In chloroform; water	98%

: 6046-93-1
copper(II) acetate monohydrate

: 5144-89-8
1,10-phenanthroline hydrate

: (1,10-Phen)Cu(OAc)2

Conditions

Conditions	Yield
In ethanol addn. of a soln. of 1,10-phenanthrolineH2O in ethanol to a filtered soln. of Cu(OAc)2H2O in ethanol; stirring the soln. for 1 h, evapn. of the solvent, washing the residue with benzene and drying in vacuo, elem. anal.;	98%

: nickel(II) chloride hexahydrate

: dicesium dodecachloro-closo-dodecaborate

: 5144-89-8
1,10-phenanthroline hydrate

: [nickel(II)(1,10-phenanthroline)3]B12Cl12

Conditions

Conditions	Yield
In ethanol; water addn. of a soln. of organic compound in boiling ethanol to a soln. of Ni-salt and B-compound in water with stirring; filtn., washing (warm water, hot ethanol, absolute ether), drying over P2O5, elem. anal.;	98%

...Expand

: manganese(II) chloride tetrahydrate

: caesium [3,3'-commo-bis(η5-nonahydro-1,2-dicarba-3-nickel-closo-decarborate)]

: 5144-89-8
1,10-phenanthroline hydrate

: [Mn(II)(1,10-phenantroline)3][bis(η5-1,2-B9C2H11)nickeliate(III)]2

Conditions

Conditions	Yield
With CH3COOH; CH3COONa; Na2SO3 In hydrogenchloride; water soln. of MnCl24H2O in acetate buffer (pH 4.56) mixed with phenH2O soln. in aq. HCl (H2O:HCl=1:4), Na2SO3 added, heated at 70°C, hot soln. Cs-Ni-complex in H2O added, stored for 12 h; ppt. filtered off, washed with H2O and C6H6, dried under vac. at 70°C; elem. anal.;	98%

...Expand

: manganese(II) chloride tetrahydrate

: cesium 1,2;1',2'-trans-bis[nonahydro-closo-decaborate]

: 5144-89-8
1,10-phenanthroline hydrate

: [tris(1,10-phenanthroline)manganese(II)] 1,2;1',2'-trans-bis[nonahydro-closo-decaborate]

Conditions

Conditions	Yield
With acetate buffer In water Mn salt dissolved in acetate buffer (pH 4.56); 1,10-phenanthroline monohydrate dissolved with stirring in acetate buffer soln.; solns. combined with stirring; soln. heated to 70°C; hot soln. of Cs2B20H18 in H2O added with stirring; ppt. formed; suspn. allowed to coagulate for 12 h; ppt. filtered off on glass frit; washed (H2O); dried (vac., 70°C);	98%

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Chemistry

Product Name: 1,10-Phenanthroline hydrate (CAS NO.5144-89-8)

Molecular Formula: C₁₂H₈N₂.H₂O
Molecular Weight: 198.22g/mol
Mol File: 5144-89-8.mol
Appearance: white crystals or powder
Melting Point: 100-104 °C(lit.)
Boiling point: 365.1 °C at 760 mmHg
Storage Temperature: Store at RT.
Flash Point: 164.8 °C
Water Solubility: <0.01 g/100 mL at 21 ºC
Stability: Stable. Incompatible with iron, other heavy metals, strong oxidizing agents, strong acids.
Enthalpy of Vaporization: 58.73 kJ/mol
Vapour Pressure: 3.38E-05 mmHg at 25°C
H-Bond Donor: 1
H-Bond Acceptor: 3
Structure Descriptors of 1,10-Phenanthroline hydrate (CAS NO.5144-89-8):
IUPAC Name: 1,10-phenanthroline hydrate
Canonical SMILES: C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.O
InChI: InChI=1S/C12H8N2.H2O/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;/h1-8H;1H2
InChIKey: PPQJCISYYXZCAE-UHFFFAOYSA-N
Product Categories: Miscellaneous; Analytical Chemistry; Chelating Reagents; Environmentally-friendly Oxidation; Ligands (Environmentally-friendly Oxidation); Phenanthrolines; Synthetic Organic Chemistry

Uses

Used as a bidentate ligand in coordination chemistry.

Safety Profile

Safety Information of 1,10-Phenanthroline hydrate (CAS NO.5144-89-8):
Hazard Codes: T Toxic ,N Dangerous
Risk Statements: 25-50/53
R20:Harmful by inhalation.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 45-60-61
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
RTECS: SF8437000
HazardClass: 6.1
PackingGroup: III
HS Code: 29339990

Specification

1,10-Phenanthroline hydrate , its CAS NO. is 5144-89-8, the synonyms are 4,5-Phenanthroline monohydrate ; AI3-22011 ; o-Phenanthroline monohydrate .