CAS No.6080-56-4,Acetic acid, lead(2+)salt, trihydrate (8CI,9CI) Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	6080-56-4
Name:	Acetic acid, lead(2+)salt, trihydrate (8CI,9CI)

Formula:	C₄H₆O₄Pb^.3H₂O
Molecular Weight:	379.335
Synonyms:	Leadacetate trihydrate (Pb(OAc)2.3H2O);Lead diacetate trihydrate;Lead(II) acetatetrihydrate;Plumbous acetate trihydrate;
EINECS:	206-104-4
Density:	2,55 g/cm3
Melting Point:	75 °C (dec.)(lit.)
Boiling Point:	117.1 °C at 760 mmHg
Flash Point:	40 °C
Solubility:	625 g/L in water
Appearance:	White crystals
Hazard Symbols:	T,N
Risk Codes:	61-33-48/22-50/53-62
Safety:	53-45-60-61
Transport Information:	UN 1616 6.1/PG 3
PSA:	80.29000
LogP:	-0.54610

Synthetic route

: 7732-18-5
water

: 64-19-7
acetic acid

: lead(II) chloride

: 6080-56-4
lead(II) acetate trihydrate

Conditions

Conditions	Yield
With sodium carbonate In acetic acid preparation of PbCO3 by treatment of PbCl2 with 1.5fold excess Na2CO3, treatment with acetic acid;;	86.5%
With Na2CO3 In acetic acid aq. acetic acid; preparation of PbCO3 by treatment of PbCl2 with 1.5fold excess Na2CO3, treatment with acetic acid;;	86.5%

...Expand

: 64-19-7
acetic acid

: 6080-56-4
lead(II) acetate trihydrate

Conditions

Conditions	Yield
With lead
With lead(II) oxide
With lead; air

: 7732-18-5
water

: lead(II) oxide

: 64-19-7
acetic acid

: 6080-56-4
lead(II) acetate trihydrate

Conditions

Conditions	Yield
In acetic acid 20% acetic acid, 380°C, stirring until a pH of 5.5 results, treatment of soln. with activated coal, further treatment at 30°C with activated coal and salicylic acid, thiosalicylic acid or thiocyanates;; product contains less than 5E-6% Fe(3+);;
In acetic acid aq. acetic acid; dissolving PbO in dild. acetic acid;;
In acetic acid aq. acetic acid; 20% acetic acid, 380°C, stirring until a pH of 5.5 results, treatment of soln. with activated coal, further treatment at 30°C with activated coal and salicylic acid, thiosalicylic acid or thiocyanates;; product contains less than 5E-6% Fe(3+);;

...Expand

: 7732-18-5
water

: lead(II) oxide

: 141-78-6
ethyl acetate

: 6080-56-4
lead(II) acetate trihydrate

Conditions

Conditions	Yield
In ethyl acetate treatment with ethyl acetate in presence of H2O;;
In ethyl acetate treatment with ethyl acetate in presence of H2O;;

...Expand

: 7439-92-1
lead

: 7732-18-5
water

: 64-19-7
acetic acid

: 6080-56-4
lead(II) acetate trihydrate

Conditions

Conditions	Yield
With air In acetic acid aq. acetic acid; treatment of Pb with aq. acetic acid in presence of air;;

...Expand

: lead(II) sulfate

: 7732-18-5
water

: 64-19-7
acetic acid

: 6080-56-4
lead(II) acetate trihydrate

Conditions

Conditions	Yield
With sodium hydroxide In acetic acid separation of sulfate with hot NaOH, react. with acetic acid;;
With NaOH In acetic acid aq. acetic acid; separation of sulfate with hot NaOH, react. with acetic acid;;

...Expand

: lead monoxide

: 7732-18-5
water

: 64-19-7
acetic acid

: 6080-56-4
lead(II) acetate trihydrate

Conditions

Conditions	Yield
In acetic acid dissolving in hot dild. acetic acid, crystn. on cooling;;
In acetic acid aq. acetic acid; dissolving in hot dild. acetic acid, crystn. on cooling;;

...Expand

: 790616-79-4
lead(II) carbonate

: 7732-18-5
water

: 64-19-7
acetic acid

: 6080-56-4
lead(II) acetate trihydrate

Conditions

Conditions	Yield
In acetic acid
In acetic acid aq. acetic acid;

...Expand

: lead(II) sulfate

: 127-09-3
sodium acetate

: 6080-56-4
lead(II) acetate trihydrate

Conditions

Conditions	Yield
In water
In water with concd. alk. acetate soln. at 25°C;;
In water with concd. alk. acetate soln. at 25°C;;
In water

: ammonium acetate

: lead(II) sulfate

: 6080-56-4
lead(II) acetate trihydrate

Conditions

Conditions	Yield
In water
In water

Raw Materials

64-19-7

Downstream Products

546-67-8

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Chemistry

Molecular Formula: C₄H₁₂O₇Pb
Formula Weight: 379.33
mp : 75 ^°C (dec.)(lit.)
bp : 280^°C
density : 2,55 g/cm³
storage temp. : 2-8^°C
Water Solubility : 625 g/L
nature of LEAD ACETATE(II), TRIHYDRATE: Lead acid hydrate three white crystalline powder or flake, and industrial products, is often brown or gray large.

Production

Massicot reacts with acetic acid to obtain LEAD ACETATE(II), TRIHYDRATE.

Toxicity Data With Reference

1.	dni-mus-ipr 20 g/kg	ARGEAR Archiv fuer Geschwulstforschung. 51 (1981),605.
2.	orl-rat TDLo:8524 mg/kg/78W-C:CAR,TER	ZAPPAN Zentralblatt fuer Allgemeine Pathologie und Pathologische Anatomie. 111 (1)(1968),1.
3.	orl-rat LD50:4665 mg/kg	JACTDZ Journal of the American College of Toxicology. 1 (1992),713.
4.	ipr-rat LD50:200 mg/kg	INMEAF Industrial Medicine. 10 (1941),15.
5.	scu-gpg LDLo:2100 mg/kg	BMJOAE British Medical Journal. 2 (1913),217.

Consensus Reports

IARC Cancer Review: Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 1 , 1972,p. 40.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . EPA Genetic Toxicology Program. Lead and its compounds are on the Community Right-To-Know List.

Safety Profile

Hazard Codes : T,N
Risk Statements : 61-33-48/22-50/53-62
Safety Statements : 53-45-60-61
RIDADR : UN 1616 6.1/PG 3
WGK Germany : 2
RTECS : OF8050000
HazardClass : 6.1
PackingGroup : III
Confirmed carcinogen with experimental carcinogenic and teratogenic data. Poison by intraperitoneal route. Moderately toxic by subcutaneous route. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of Pb. See also LEAD COMPOUNDS.

Standards and Recommendations

OSHA PEL: TWA 0.05 mg(Pb)/m³
NIOSH REL: (Inorganic Lead) TWA 0.10 mg(Pb)/m³