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793-24-8

Basic Information
CAS No.: 793-24-8
Name: 1,4-Benzenediamine,N1-(1,3-dimethylbutyl)-N4-phenyl-
Article Data: 19
Cas Database
Molecular Structure:
Molecular Structure of 793-24-8 (1,4-Benzenediamine,N1-(1,3-dimethylbutyl)-N4-phenyl-)
Formula: C18H24N2
Molecular Weight: 268.402
Synonyms: 1,4-Benzenediamine,N-(1,3-dimethylbutyl)-N'-phenyl- (9CI);p-Phenylenediamine,N-(1,3-dimethylbutyl)-N'-phenyl- (7CI,8CI);4-(1,3-Dimethylbutylamino)diphenylamine;6PPD;Antage 6C;Antozite 67;CD 13;CI;DBDA;DMBPD;Diafen FDMB;Flexzone 7F;Flexzone 7P;Forte 6C;N-(1,3-Dimethylbutyl)-N'-phenyl-1,4-benzenediamine;N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine;N-Phenyl-N'-(1,3-dimethylbutyl)-1,4-phenylenediamine;Nocrac 6C;Ozonone 6C;Permanax 120;Santoflex 13F;UOP 562;UOP 588;Vulkanox 4020;Vulkanox 4020LG;Wingstay 300;
EINECS: 212-344-0
Density: 1.039 g/cm3
Melting Point: 45-46 °C
Boiling Point: 412.3 °C at 760 mmHg
Flash Point: 245.8 °C
Solubility: <0.1 g/100 mL at 17 °C in water
Appearance: Purple flakes
Hazard Symbols: N/A
Risk Codes: N/A
Safety:
Transport Information: N/A
PSA: 24.06000
LogP: 5.42270
Synthetic route
108-10-1

4-methyl-2-pentanone

101-54-2

N-phenylphenylene-1,4-diamine

793-24-8

N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions
ConditionsYield
With hydrogen at 99.84℃; under 18751.9 Torr; for 4h; Catalytic behavior; Reagent/catalyst; Time; Autoclave;100%
With hydrogen; pyrographite at 20 - 150℃; under 22052.2 Torr; for 0.1h; Autoclave;99.4%
With platinum on activated charcoal; isopropyl alcohol at 50 - 150℃; under 36775.4 Torr; Hydrogenation;
63302-40-9

C18H22N2

793-24-8

N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions
ConditionsYield
With palladium on activated charcoal; hydrogen In 5,5-dimethyl-1,3-cyclohexadiene at 100℃; under 7500.75 Torr; Solvent; Temperature;92.6%
156-10-5

p-nitrosodiphenylamine

108-10-1

4-methyl-2-pentanone

793-24-8

N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions
ConditionsYield
With platinum on activated charcoal; isopropyl alcohol at 50 - 150℃; under 25742.8 Torr; Hydrogenation;
836-30-6

4-ntrophenyl(phenyl)amine

108-10-1

4-methyl-2-pentanone

793-24-8

N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions
ConditionsYield
With platinum on activated charcoal; isopropyl alcohol at 50 - 150℃; under 25742.8 Torr; Hydrogenation;

N-[1,3-Dimethyl-but-(E)-ylidene]-N'-phenyl-benzene-1,4-diamine

793-24-8

N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions
ConditionsYield
With formic acid; palladium on activated charcoal at 85℃; Yield given;
836-30-6

4-ntrophenyl(phenyl)amine

793-24-8

N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 5percent Pd/C
2: 5percent palladium-on-carbon / 85 °C
3: HCOOH / 5percent Pd/C / 85 °C
View Scheme
Multi-step reaction with 3 steps
1: formic acid / 5percent Pd/C / 85 °C
2: 5percent palladium-on-carbon / 85 °C
3: HCOOH / 5percent Pd/C / 85 °C
View Scheme
108-10-1

4-methyl-2-pentanone

793-24-8

N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 5percent palladium-on-carbon / 85 °C
2: HCOOH / 5percent Pd/C / 85 °C
View Scheme
101-54-2

N-phenylphenylene-1,4-diamine

793-24-8

N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 5percent palladium-on-carbon / 85 °C
2: HCOOH / 5percent Pd/C / 85 °C
View Scheme
2406-04-4

4-(phenylimino)cyclohexa-2,5-dienone

793-24-8

N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions
ConditionsYield
In methanol
108-10-1

4-methyl-2-pentanone

101-54-2

N-phenylphenylene-1,4-diamine

A

793-24-8

N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

B

63302-40-9

C18H22N2

Conditions
ConditionsYield
With palladium on activated charcoal; hydrogen at 200℃; under 30003 Torr; Reagent/catalyst;
With hydrogen at 160℃; under 22502.3 Torr; for 4h; Autoclave;
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Chemistry

IUPAC Name: 1-N-(4-methylpentan-2-yl)-4-N-Phenylbenzene-1,4-diamine
Synonyms:1,4-Benzenediamine, N~1~-(1,3-dimethylbutyl)-N~4~-phenyl- ; 1,4-Benzenediamine, N~1~-(1,3-dimethylbutyl)-N~4~-phenyl- ; N-(1,3-dimethylbutyl)-N'-Phenylbenzene-1,4-diamine ; N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine ; N-(4-Methyl-2-pentanyl)-N'-phenyl-1,4-benzenediamine
Product Categories: Industrial/Fine Chemicals;Antidegradants
Molecular Structure :
Molecular Formula: C18H24N2
Molecular Weight : 268.40
CAS NO: 793-24-8
EINECS: 212-344-0
Mol File: 793-24-8.mol
Melting point: 45-46 ºC
Boiling point: 260 ºC
Flash point: 204 ºC
Density: 1.039 g/cm3
Appearance:Purple flakes
Index of Refraction: 1.599
Surface Tension: 40.9 dyne/cm
Enthalpy of Vaporization: 66.49 kJ/mol
Vapour Pressure: 5.22E-07 mmHg at 25°C
Water solubility <0.1 g/100 mL at 17 ºC
Appearance: N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine (CAS NO. 793-24-8) is gray-black solid

Uses

1.N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine (CAS NO. 793-24-8) is used for anti-ozone agents and antioxidants for natural rubber and synthetic rubber.
2.N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine (CAS NO. 793-24-8) is used for fine effectiveness on the protection of ozone and flex fatigue cracking .

Production

Using the 4 - amino-2-aniline and methyl isobutyl ketone, catalytic,with hydrogenation condensation, Then, N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine (CAS NO. 793-24-8) is derived.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rabbit LD50 skin > 7940mg/kg (7940mg/kg) BEHAVIORAL: FOOD INTAKE (ANIMAL)

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)
Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 67, 1990.
rat LD50 oral 3580mg/kg (3580mg/kg) SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE

BEHAVIORAL: FOOD INTAKE (ANIMAL)

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 67, 1990.

Safety Profile

RTECS ST0900000

Specification

1.Air & Water Reactions :N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine may be sensitive to prolonged exposure to air. Insoluble in water.
2.Reactivity Profile :You should protect N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine (CAS NO. 793-24-8) from exposure to strong oxidizing agents such as chlorine or hydrogen peroxide. N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine will ignite if heated strongly.
3.Fire Hazard: N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine is combustible.

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