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| CAS No.: | 85-01-8 |
|---|---|
| Name: | Phenanthrene |
| Article Data: | 536 |
| Cas Database | |
| Molecular Structure: | |
|
|
|
| Formula: | C14H10 |
| Molecular Weight: | 178.233 |
| Synonyms: | NSC26256;[3]Helicene;AI3-00790;CCRIS 1233;HSDB 2166;Phenanthren [German];Phenanthrin;Ravatite;UNII-448J8E5BST; |
| EINECS: | 201-581-5 |
| Density: | 1.13 g/cm3 |
| Melting Point: | 98-100 °C(lit.) |
| Boiling Point: | 337.355 °C at 760 mmHg |
| Flash Point: | 146.606 °C |
| Solubility: | insoluble in water |
| Appearance: | white crystals |
| Hazard Symbols: |
 Xn, N
|
| Risk Codes: | 36/37/38-50-40-67-65-11-52/53-39-23/24/25-63-43-45-20/21/22 |
| Safety: | 26-60-61-36-29-62-45-16-7-24/25-23-53-37/39-22 |
| Transport Information: | UN 3077 9/PG 3 |
| PSA: | 0.00000 |
| LogP: | 3.99300 |
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IUPAC Name: Phenanthrene
Synonyms of Phenanthrene (CAS NO.85-01-8): AI3-00790 ; CCRIS 1233 ; EINECS 201-581-5 ; HSDB 2166 ; NSC 26256 ; Phenanthren ; Phenanthren [German] ; Phenanthrin ; Ravatite ; UNII-448J8E5BST ; Phenanthrene, pure ;
Coal tar pitch volatiles: phenanthrene
CAS NO: 85-01-8
Classification Code: Mutation data ; Tumor data
Molecular Formula: C14H10
Molecular Weight: 178.2292
Molecular Structure:
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Melting Point: 98-100 °C
Index of Refraction: 1.714
Molar Refractivity: 61.93 cm3
Molar Volume: 157.6 cm3
Surface Tension: 47.9 dyne/cm
Density: 1.13 g/cm3
Flash Point: 146.6 °C
Enthalpy of Vaporization: 55.76 kJ/mol
Boiling Point: 337.4 °C at 760 mmHg
Vapour Pressure: 0.000206 mmHg at 25°C
Phenanthrene (CAS NO.85-01-8) is commonly used like labelled polycyclic aromatic hydrocarbons as micropollutants.And it's generally used for the preparation of phenanthrenequinone, synthetic resins, pesticides, preservatives, etc.
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intraperitoneal | 700mg/kg (700mg/kg) | JNCI, Journal of the National Cancer Institute. Vol. 62, Pg. 911, 1979. | |
| mouse | LD50 | intravenous | 56mg/kg (56mg/kg) | U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#00190, | |
| mouse | LD50 | oral | 700mg/kg (700mg/kg) | Hygiene and Sanitation Vol. 29(6), Pg. 19, 1964. |
IARC Cancer Review: Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 32 ,1983,p. 419.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.
Hazard Codes of Phenanthrene (CAS NO.85-01-8): 
Xn,
N,
F,
T
Risk Statements: 36/37/38-50-40-67-65-11-52/53-39-23/24/25-63-43-45-20/21/22
R36/37/38: Irritating to eyes, respiratory system and skin.
R50: Very toxic to aquatic organisms.
R40: Limited evidence of a carcinogenic effect.
R67: Vapours may cause drowsiness and dizziness.
R65: Harmful: may cause lung damage if swallowed.
R11: Highly flammable.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R39: Danger of very serious irreversible effects.
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
R63: Possible risk of harm to the unborn child.
R43: May cause sensitization by skin contact.
R45: May cause cancer.
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
Safety Statements: 26-60-61-36-29-62-45-16-7-24/25-23-53-37/39-22
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S60: This material and its container must be disposed of as hazardous waste.
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
S36: Wear suitable protective clothing.
S29: Do not empty into drains.
S62: If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S16: Keep away from sources of ignition.
S7: Keep container tightly closed.
S24/25: Avoid contact with skin and eyes.
S23: Do not breathe vapour.
S53: Avoid exposure - obtain special instructions before use.
S37/39: Wear suitable gloves and eye/face protection.
S22: Do not breathe dust.
RIDADR: UN 3077 9/PG 3
WGK Germany: 2
RTECS: SF7175000
F: 8
HazardClass: 9
PackingGroup: III
Hazardous Substances Data: 85-01-8(Hazardous Substances Data)
Poison by intravenous route. Moderately toxic by ingestion. Mutation data reported. A human skin photosensitizer. Questionable carcinogen with experimental neoplastigenic and tumorigenic data by skin contact. Combustible when exposed to heat or flame; can react vigorously with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
OSHA PEL: TWA 0.2 mg/m3
For occupational chemical analysis use OSHA: #ID-58 or NIOSH: Polynuclear Aromatic Hydrocarbons (HPLC), 5506; (GC), 5515.
