- 1-Azaadamantanes from Substituted Phloroglucinols
The heterocycles 3 are synthesised from substituted phloroglucinols 2 and hexamethylenetetramine in one step.Special chemical properties of these 1-azaadamantanes are, for example, the formation of a BH3-complex 4 and the stereoselective reduction to the trialcohol 6.The reaction of 6 with trimethoxymethane yields the heterodiamantane.
- Risch, Nikolaus
p. 4849 - 4856
(2007/10/02)