Welcome to LookChem.com Sign InJoin Free

Cas Database

4435-14-7

4435-14-7

Identification

  • Molecular Formula:C8H13N

  • EINECS:

Synonyms:RARECHEM AK ML 0197;1-Cyclohexaneacetonitrile;1-Cyclohexyl acetonitrile;Cyclohexyl-acetonitrile;

Post Buying Request Now
Entrust LookChem procurement to find high-quality suppliers faster

Safety information and MSDS

  • Pictogram(s):

  • Hazard Codes:

  • Signal Word:

  • Hazard Statement:

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
  • Delivery
  • Purchase
  • Manufacture/Brand:Acrotein
  • Product Description:Cyclohexaneacetonitrile 97%
  • Packaging:5g
  • Price:$ 247.5
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:AK Scientific
  • Product Description:2-Cyclohexylacetonitrile
  • Packaging:5g
  • Price:$ 291
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Ambeed
  • Product Description:2-Cyclohexylacetonitrile 97%
  • Packaging:10g
  • Price:$ 323
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Ambeed
  • Product Description:2-Cyclohexylacetonitrile 97%
  • Packaging:25g
  • Price:$ 608
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Ambeed
  • Product Description:2-Cyclohexylacetonitrile 97%
  • Packaging:250mg
  • Price:$ 21
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Ambeed
  • Product Description:2-Cyclohexylacetonitrile 97%
  • Packaging:1g
  • Price:$ 46
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Ambeed
  • Product Description:2-Cyclohexylacetonitrile 97%
  • Packaging:5g
  • Price:$ 168
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:1-CYCLOHEXYL ACETONITRILE 95.00%
  • Packaging:1G
  • Price:$ 648.81
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:1-CYCLOHEXYL ACETONITRILE 95.00%
  • Packaging:2.5G
  • Price:$ 852.21
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:1-CYCLOHEXYL ACETONITRILE 95.00%
  • Packaging:5G
  • Price:$ 1005.43
  • Delivery:In stock
  • Buy Now

Relevant articles and documentsAll total 30 Articles be found

MITOCHONDRIA-TARGETING PEPTIDES

-

Page/Page column 52; 53, (2019/07/19)

Disclosed are non-natural peptides useful for the treatment and prevention of ischemia-reperfusion injury (e.g., cardiac ischemia-reperfusion injury) or myocardial infarction.

Formal reductive addition of acetonitrile to aldehydes and ketones

Muratov, Karim,Kuchuk, Ekaterina,Vellalath, Sreekumar,Afanasyev, Oleg I.,Moskovets, Alexei P.,Denisov, Gleb,Chusov, Denis

supporting information, p. 7693 - 7701 (2018/11/02)

An efficient and highly productive rhodium-catalyzed method for the synthesis of nitriles employing aldehydes or ketones, methyl cyanoacetate, water and carbon monoxide as starting materials has been developed. Simple rhodium chloride without any ligands can be used. The fine tuning of the substrate can lead to the activity higher than 5000 TON.

Electrochemical Tandem Olefination and Hydrogenation Reaction with Ammonia

Zhang, Xiaofeng,Jiang, Runze,Cheng, Xu

, p. 16016 - 16025 (2021/08/24)

An electrochemical Horner-Wadsworth-Emmons/hydrogenation tandem reaction was achieved using ammonia as electron and proton donors. The reaction could give two-carbon-elongated ester and nitrile from aldehyde or ketones directly. This reaction could proceed with a catalytic amount of base or even without a base. The ammonia provides both the electron and proton for this tandem reaction and enables the catalyst-free hydrogenation of an α,β-unsaturated HWE intermediate. More than 40 examples were reported, and functional groups, including heterocycles and hydroxyl, were tolerated.

Corresponding amine nitrile and method of manufacturing thereof

-

Paragraph 0153; 0154; 0155; 0162; 0163, (2018/05/07)

The invention relates to a manufacturing method of nitrile. Compared with the prior art, the manufacturing method has the characteristics of significantly reduced using amount of an ammonia source, low environmental pressure, low energy consumption, low production cost, high purity and yield of a nitrile product and the like, and nitrile with a more complex structure can be obtained. The invention also relates to a method for manufacturing corresponding amine from nitrile.

A mineralogically-inspired silver-bismuth hybrid material: An efficient heterogeneous catalyst for the direct synthesis of nitriles from terminal alkynes

?tv?s, Sándor B.,Mészáros, Rebeka,Varga, Gábor,Kocsis, Marianna,Kónya, Zoltán,Kukovecz, ákos,Pusztai, Péter,Sipos, Pál,Pálinkó, István,Fül?p, Ferenc

, p. 1007 - 1019 (2018/03/13)

The synthesis and characterization of a silver-containing hybrid material is reported as a novel heterogeneous noble metal catalyst. In order to eliminate the need for traditional immobilization techniques, and to create a solid material with structurally-bound silver catalytic centers, the layered structure of a naturally occurring mineral served as the basis of the initial catalyst design. The novel material was prepared by means of the urea-mediated homogeneous precipitation of the corresponding metal nitrates, and was fully characterized by means of diverse instrumental techniques (X-ray diffractometry, Raman, IR, UV-Vis, EPR, X-ray photoelectron spectroscopies, thermal methods as well as atomic force, scanning and transmission electron microscopies). The as-prepared material exhibited outstanding activity in silver-catalyzed CC bond activation to yield organic nitriles directly from terminal alkynes with less environmental concerns as compared to the classical synthesis methods. The effects of the reaction time, the temperature, as well as the role of various solvents, nitrogen sources and additives were carefully scrutinized in order to achieve high-yielding and selective nitrile formation. The heterogeneous nature of the reaction was verified and the solid catalyst was recycled and reused numerous times without loss of its activity or degradation of its structure, thereby offering a sustainable synthetic methodology.

Process route upstream and downstream products

Process route

potassium cyanide
151-50-8

potassium cyanide

C<sub>22</sub>H<sub>36</sub>N<sub>2</sub>O<sub>2</sub>S

C22H36N2O2S

2-cyclohexylacetonitrile
4435-14-7

2-cyclohexylacetonitrile

Conditions
ConditionsYield
Inmethanol;for 2h; Yield given; Heating;
C<sub>18</sub>H<sub>30</sub>N<sub>2</sub>O<sub>2</sub>SSi
142981-64-4

C18H30N2O2SSi

2-cyclohexylacetonitrile
4435-14-7

2-cyclohexylacetonitrile

Conditions
ConditionsYield
Withtetrabutylammonium tetrafluoroborate;Indichloromethane;Yield given; Ambient temperature; electrolysis;
sodium cyanide
143-33-9,25596-52-5

sodium cyanide

cyclohexylmethyl chloride
1072-95-3

cyclohexylmethyl chloride

2-cyclohexylacetonitrile
4435-14-7

2-cyclohexylacetonitrile

acetonitrile
75-05-8,26809-02-9

acetonitrile

hydrogen cyanide
74-90-8

hydrogen cyanide

2-cyclohexylacetonitrile
4435-14-7

2-cyclohexylacetonitrile

methyl cyclohexane
82166-21-0

methyl cyclohexane

acrylonitrile
107-13-1,25014-41-9

acrylonitrile

propiononitrile
107-12-0

propiononitrile

cyclohexene
110-83-8

cyclohexene

Conditions
ConditionsYield
Ingas;under 0.1 - 0.3 Torr; Mechanism; Radiofrequency discharge, various flow rate; var. reaction partners;
acetonitrile
75-05-8,26809-02-9

acetonitrile

cyclohexene
110-83-8

cyclohexene

bicyclohexyl-2,2'-diene
1541-20-4

bicyclohexyl-2,2'-diene

1,2-Cyclohexanediol
931-17-9

1,2-Cyclohexanediol

2-cyclohexylacetonitrile
4435-14-7

2-cyclohexylacetonitrile

Cyclohex-2-enol
822-67-3

Cyclohex-2-enol

Conditions
ConditionsYield
Withdipotassium peroxodisulfate;silver nitrate;Inwater; acetonitrile;at 60 ℃; for 6h; Further byproducts given;
16%
4.5%
5%
20%
acetonitrile
75-05-8,26809-02-9

acetonitrile

cyclohexene
110-83-8

cyclohexene

2-cyclohexylacetonitrile
4435-14-7

2-cyclohexylacetonitrile

Conditions
ConditionsYield
Withsilver trifluoromethanesulfonate; at 25 ℃; Irradiation;
acetonitrile
75-05-8,26809-02-9

acetonitrile

cyclohexene
110-83-8

cyclohexene

2-cyclohexylacetonitrile
4435-14-7

2-cyclohexylacetonitrile

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
Withdihydrogen peroxide; for 15h; Yield given. Yields of byproduct given; Irradiation;
sodium cyanide
143-33-9,25596-52-5

sodium cyanide

cyclohexylmethyl alcohol
100-49-2

cyclohexylmethyl alcohol

2-cyclohexylacetonitrile
4435-14-7

2-cyclohexylacetonitrile

copper(I) cyanide
150464-47-4

copper(I) cyanide

methylenecyclohexane
1192-37-6

methylenecyclohexane

2-cyclohexylacetonitrile
4435-14-7

2-cyclohexylacetonitrile

potassium cyanide
151-50-8

potassium cyanide

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

2-cyclohexylacetonitrile
4435-14-7

2-cyclohexylacetonitrile

Conditions
ConditionsYield
WithMacroreticular St-DVB copolymer;Yield given. Multistep reaction; 1.) EtOH, reflux, 0.5 h, 2.) MeOH, reflux, 72 h;

Global suppliers and manufacturers

Global( 28) Suppliers
  • Company Name
  • Business Type
  • Contact Tel
  • Emails
  • Main Products
  • Country
  • Amadis Chemical Co., Ltd.
  • Business Type:Lab/Research institutions
  • Contact Tel:86-571-89925085
  • Emails:sales@amadischem.com
  • Main Products:29
  • Country:China (Mainland)
  • Career Henan Chemical Co
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-371-86658258
  • Emails:purchase@coreychem.com
  • Main Products:137
  • Country:China (Mainland)
  • SAGECHEM LIMITED
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-571-86818502
  • Emails:will@sagechem.com
  • Main Products:32
  • Country:China (Mainland)
  • Antimex Chemical Limied
  • Business Type:Lab/Research institutions
  • Contact Tel:0086-21-50563169
  • Emails:anthony@antimex.com
  • Main Products:151
  • Country:China (Mainland)
  • Chemlyte Solutions
  • Business Type:Other
  • Contact Tel:+86-189 8945 5137
  • Emails:sales@chemlytesolutions.com
  • Main Products:200
  • Country:China (Mainland)
  • LEAP CHEM Co., Ltd.
  • Business Type:Trading Company
  • Contact Tel:0571-87317139
  • Emails:market15@leapchem.com
  • Main Products:89
  • Country:China (Mainland)
close

Please post your buying leads,so that our qualified suppliers will soon contact you!

*Required Fields

CAS No.:
* Product Name:
* Your email:

Your email will be used to sign-in to LookChem.com
* Requirements:
* Valid for:
 
Post Buying Request Now
close
Remarks: The blank with*must be completed