Synonyms:BENZALDEHYDE (RING-D5);BENZALDEHYDE-D5;BENZALDEHYDE-2,3,4,5,6-D5;BENZALDEHYDE-D6, 98 ATOM % D;BENZALDEHYDE (D6, 98%) (+0.1% HYDROQUINONE)
- Melting Point:−26 °C(lit.)
- Boiling Point:178-179 °C(lit.)
- Density:1.094 g/mL at 25 °C
- Flash Point:145 °F
- Vapor Density:N/A
- Refractive Index:n20/D 1.545(lit.)
- Storage Temp.:N/A
Benzaldehyde-d6 Safety information and MSDS
H302 Harmful if swallowed
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/…if you feel unwell.
P330 Rinse mouth.
P501 Dispose of contents/container to ...
·Composition/information on ingredients:
|Chemical name||Common names and synonyms||CAS number||EC number||Concentration|
General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.
·Accidental release measures:
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.
Benzaldehyde-d6 Relevant articlesAll total 33 Articles be found
Rh(III)-Catalyzed [4+2] Cyclization of 2-Aryl-1H-benzo[d]imidazoles with Maleimides via C-H Activation
Deng, Chen,Li, Changchang,Yao, Jinzhong,Jin, Quanli,Miao, Maozhong,Zhou, Hongwei
supporting information, p. 3552 - 3558 (2021/07/26)
A rhodium-catalyzed formal [4+2]-cyclization of 2-aryl-1H-benzo[d]imidazoles with maleimides through C?H bond activation process is described here. Such an approach enables selectively construct a series of functionalized cis-dihydro-benzimidazo[2,1-a]iso
One-Pot Construction of Diverse Products using Versatile Cyclopropenones
Huang, Tianle,Yang, Chunyan,Shi, Yuesen,Chen, Jian,Wang, Ting,Guo, Xiaoyu,Liu, Xuexin,Ding, Haosheng,Wu, Zhouping,Hai, Li,Wu, Yong
supporting information, p. 4899 - 4904 (2021/09/14)
Tunable C?H activation cascade reactions between quinazolinones and cyclopropenones have been developed. Notably, cyclopropenones, acting as multi-functional building blocks, could be assembled to construct up to 10 distinct heterocyclic scaffolds in a one-pot manner. (Figure presented.).
Nonheme Diiron Oxygenase Mimic That Generates a Diferric-Peroxo Intermediate Capable of Catalytic Olefin Epoxidation and Alkane Hydroxylation including Cyclohexane
Oloo, Williamson N.,Szávuly, Miklós,Kaizer, József,Que, Lawrence
, p. 37 - 41 (2021/12/27)
Herein are described substrate oxidations with H2O2 catalyzed by [FeII(IndH)(CH3CN)3](ClO4)2 [IndH = 1,3-bis(2′-pyridylimino)isoindoline], involving a spectroscopically characterized (μ-oxo)(μ-1,2-peroxo)diiron(III) intermediate (2) that is capable of olefin epoxidation and alkane hydroxylation including cyclohexane. Species 2 also converts ketones to lactones with a decay rate dependent on [ketone], suggesting direct nucleophilic attack of the substrate carbonyl group by the peroxo species. In contrast, peroxo decay is unaffected by the addition of olefins or alkanes, but the label from H218O is incorporated into the the epoxide and alcohol products, implicating a high-valent iron-oxo oxidant that derives from O-O bond cleavage of the peroxo intermediate. These results demonstrate an ambiphilic diferric-peroxo intermediate that mimics the range of oxidative reactivities associated with O2-activating nonheme diiron enzymes.
Metal- And additive-free C-H oxygenation of alkylarenes by visible-light photoredox catalysis
García Manche?o, Olga,Kuhlmann, Jan H.,Pérez-Aguilar, María Carmen,Piekarski, Dariusz G.,Uygur, Mustafa
, p. 3392 - 3399 (2021/05/21)
A metal- and additive-free methodology for the highly selective, photocatalyzed C-H oxygenation of alkylarenes under air to the corresponding carbonyls is presented. The process is catalyzed by an imide-acridinium that forms an extremely strong photooxidant upon visible light irradiation, which is able to activate inert alkylarenes such as toluene. Hence, this is an easy to perform, sustainable and environmentally friendly oxidation that provides valuable carbonyls from abundant, readily available compounds.
Divergent Construction of Diverse Scaffolds through Catalyst-Controlled C?H Activation Cascades of Quinazolinones and Cyclopropenones
Shi, Yuesen,Huang, Tianle,Wang, Ting,Chen, Jian,Liu, Xuexin,Wu, Zhouping,Huang, Xiaofang,Zheng, Yao,Yang, Zhongzhen,Wu, Yong
supporting information, p. 13346 - 13351 (2021/08/12)
A transition-metal-catalyzed C?H activation cascade strategy to rapidly construct diverse quinazolinone derivatives in a one-pot manner is reported. The catalysts play an important role in the different transformations. Additionally, the procedure is scal
Benzaldehyde-d6 Synthetic route And Reaction conditions
WithFeII(1,3-bis(2'-pyridylimino)isoindoline)(CH3CN)3(H2O)0.5(ClO4)2; dihydrogen peroxide;Inacetonitrile;at 25 ℃; Kinetics; Inert atmosphere;
Withoxygen; at 25 ℃; for 4h; Kinetics; Irradiation;
Multi-step reaction with 2 steps
1: sulfuric acid; chromium(VI) oxide / 0.17 h / 0 - 10 °C
2: sulfuric acid / ethanol / 0.5 h / Reflux
Withdihydrogen peroxide; [FeII(1,3-bis(2′-pyridylimino)isoindoline)(CH3CN)3](ClO4)2;Inacetonitrile;at 25 ℃; Kinetics;
Yield given. Multistep reaction;
phenyl N-tosyl imine
phenyl N-tosyl imine
Benzaldehyde-d6 Raw materials
Benzaldehyde-d6 Target Products
- Lab/Research institutionsTrading CompanyManufacturers
- Product LicenseEnterprise AuthenticationISOGMPFDAHALAL
- China (Mainland)(2)India(1)
- 1,1-dimethylethyl methyl(2-phenyl-2-oxoethyl)carbamate
- tris(para-trifluoromethyl)phenyl phosphine
- p-nitrobenzaldehyde diethyl acetal
- methyl 2-methoxy-5-iodobenzoate
- ethylene glycol glycolate
- (R)-α-(phenylthio)propanoic acid
- Total:3 Page 1 of 1 1
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