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HYDROXYLAMINE

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Basic Information

Name: CAS No.:
Molecular Structure:

Molecular Structure of 7803-49-8 (Hydroxylamine)

Formula: Molecular Weight :
Synonyms:

HDA;Hydroxyamine; Telclean 1200A

EINECS: Density: Melting Point: Boiling Point: Flash Point: Solubility: Appearance: Hazard Symbols: Risk Codes: Transport Information: MSDS:

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52-90-4
79-24-3
69645-51-8
683-62-5
3638-64-0
7439-95-4
216445-62-4
7783-99-5

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O-(2-(vinyloxy)ethyl)hydroxylamine

Cas No: 391212-29-6 Min.Order: FOB Price:

Dalian Bajia import and export co. ltd have great engineer make more great quality cargo will meet all customer request . Now we have own lab for cargo even my cargo is so less but quality and quantity and shippment will be promise as we are pro

N,N-Diethylhydroxylamine CAS:3710-84-7 Safe delivery Free of customs clearance

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What's our company advantages 1. Government support guarantees good company credibility and finance safe. 2. Finer chem is confident at the quality of the products, and would like to supply free sample to our customers. 3. Factory locates in n

Hydroxylamine HCL

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Factory Supply Hydroxylamine

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The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Hydroxylamine

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Hydroxylamine 7803-49-8

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Shanghai Upbio Tech Co.,Ltd

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Large Stock 99.0% HYDROXYLAMINE 7803-49-8 Producer

Cas No: 7803-49-8 Min.Order: FOB Price:

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience 2. Free samples will be provided,ensure specifications and quality are right for customer 3. Customers will receive the most professional techn

In stock hydroxylamine

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Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Appearance:Unstable white large flakes or needle crystals

Hydroxylamine /cas:5470-11-1/Hydroxylamine material

Cas No: 5470-11-1 Min.Order: FOB Price: / Kilogram

Name:Hydroxylamine CAS no:5470-11-1 Grade:Scientific research and export Molecular formula: H4ClNO Molecular weight: 69.4909 Product Quality 12 years of chemical raw materials Mature operation of the industry System stability Data

O-TritylhydroxylaMine

Cas No: 31938-11-1 Min.Order: FOB Price: / Kilogram

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

China Supplier High Quality 99% Purity CAS #7803-49-8 Powder

Cas No: 7803-49-8MSDS/COA Download Min.Order: FOB Price: / Kilogram

Name: Hydroxylamine Molecular Formula: H3NO CAS Number: 7803-49-8 Package: According to the customer's request Export Port: Wuhan, Shanghai, Shenzhen, Guangzhou, etc, Purity: 99% min Storage condition: Refrigerator store (within th

Hydroxylamine

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Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Good quality Hydroxylamine CAS NO.5470-11-1

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Hydroxylamine

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Henan Coreychem co., LTD focus on high complex new type intermediates and fine chemical custom synthesis,scale-up production and rare chemicals trade.Product category including Intermediates&API,Catalyst and Electronic Chemicals.Covering 811 sq

Career Henan Chemical Co

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hydroxylamine,freebase HYDROXYLAMINE Hydroxylamine solution

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HYDROXYLAMINE

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Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

Afine Chemicals Limited

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High Quality Hydroxylamine

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HangYu Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. HangYu Chemical consis

Hydroxylamine

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HYDROXYLAMINE

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Hydroxylamine

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HYDROXYLAMINE

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HYDROXYLAMINE Basic information Product Name: HYDROXYLAMINE Synonyms: hydroxylamine,freebase;hydroxylaminefree-base;NH2OH;Oxammonium;Oxyammonia;FH-50;FH-50TM;HYDROXYLAMINE CAS: 7803-49-8 MF: H3NO MW: 33.03 EINECS: 232-259-2 Product

Hydroxylamine solution

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hydroxylamine/ 7803-49-8

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Hydroxylamine

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Hydroxylamine

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R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

HYDROXYLAMINE

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Hydroxylamine

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Hydroxylamine

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Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Antimex Chemical Limied

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Hydroxylamine

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Comply with CP,JP,EP,US GradeAppearance:White Solid Storage:Stored under room temperature in cool and dry place Package:In 25KG paper or plastic drums Application:Used as pharmaceutical Intermeidate Transportation:Shipped as non- dangerous chemicals

Hydroxylamine

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low price and good quality Application:It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and D

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Chemistry

Chemistry informtion about Hydroxylamine (CAS NO.7803-49-8) is:
IUPAC Name: Hydroxylamine
Synonyms: Hydroxylamine,Freebase ; Hydroxylaminefree-Base ; Nh2oh ; Oxammonium ; Oxyammonia ; Fh-50 ; Fh-50tm ; Hydroxylamine
MF: H3NO
MW: 33.03
EINECS: 232-259-2
Melting Point: 7°C
Density: 1.111 g/cm3
Boiling Point: 56.5 °C at 760 mmHg
Vapour Pressure: 179 mmHg at 25°C
Enthalpy of Vaporization: 34.9 kJ/mo
Refractive Index: n20/D 1.393
Merck: 13,4853
Stability: Stable. Incompatible with oxidizing agents, potassium dichromate, chromium trioxide, zinc, calcium, copper, sodium, ammonia, carbonyls, phosphorus halides, pyridine, hypochlorites.
Following is the molecular structure of  Hydroxylamine (CAS NO.7803-49-8) is:

Uses

 Hydroxylamine (CAS NO.7803-49-8) and its salts are commonly used as reducing agents in a myriad of organic and inorganic reactions. They can also act as antioxidants for fatty acids. Some non-chemical uses include removal of hair from animal hides and photography developing solutions. It can also be used to highly selectively cleave asparaginyl-glycine peptide bonds in peptides and proteins. It also bonds to and permanently disables (poisons) heme-containing enzymes. It is used as an irreversible inhibitor of the oxygen-evolving complex of photosynthesis on account of its similar structure to water.

Production

 NH2OH can be synthesized via several routes.
The first route is via Raschig synthesis: aqueous ammonium nitrite is reduced by HSO4 and SO2 at 0°C to yield a hydroxylamido-N,N-disulfate anion:
NH4NO2 + 2 SO2 + NH3 + H2O → 2 NH4+ + N(OH)(OSO2)22
This anion is then hydrolyzed to give (NH3OH)2SO4:
N(OH)(OSO2)22+ H2O → NH(OH)(OSO2)− + HSO4
2 NH(OH)(OSO2)− + 2 H2O → (NH3OH)2SO4
Solid NH2OH can be collected by treatment with liquid ammonia. Ammonium sulfate, (NH4)2SO4, a side-product insoluble in liquid ammonia, is removed by filtration; the liquid ammonia is evaporated to give the desired product.Another route is to make hydroxylammonium salts which can then be converted to hydroxylamine.
(NH3OH)Cl + NaOBu → NH2OH + NaCl + BuOH
Hydroxylamine can also be produced by the reduction of nitrous acid or potassium nitrate with bisulfite:
HNO2 + 2 HSO3 → N(OH)(OSO2)22+ H2O → NH(OH)(OSO2) + HSO4
NH(OH)(OSO2) + H3O+ (100 °C/1 h) → NH3(OH)+ + HSO4

Toxicity Data With Reference

1.    

mmo-omi 1 mg/L

    MUREAV    Mutation Research. 74 (1980),113.
2.    

slt-dmg-unr 45 mmol/L/48H

    MUREAV    Mutation Research. 120 (1983),233.
3.    

dni-hmn:hla 10 mmol/L

    MUREAV    Mutation Research. 93 (1982),447.
4.    

sce-ham:lng 5 mmol/L

    HUGEDQ    Human Genetics. 54 (1980),155.
5.    

ipr-rat LD50:59 mg/kg

    CNREA8    Cancer Research. 26 (1966),1448.
6.    

scu-rat LD50:29 mg/kg

    JPETAB    Journal of Pharmacology and Experimental Therapeutics. 119 (1957),444.
7.    

ipr-mus LD50:60 mg/kg

    JPETAB    Journal of Pharmacology and Experimental Therapeutics. 165 (1969),30.

Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Safety Profile

a poison by intraperitoneal and subcutaneous routes. a corrosive irritant to the eyes, skin, and mucous membranes. locally it is irritating, and systemically it can cause methemoglobinemia. human mutation data reported. dangerous fire hazard when exposed to heat, flame, and oxidizers. may ignite spontaneously in air if a large surface area is exposed (e.g., precipitate on paper). explodes in air when heated above 70°c. explosive reaction with potassium dichromate, chromium trioxide, powdered zinc + heat. forms the heat-sensitive explosive bis(hydroxylamide) in reaction with zinc or calcium. ignites on contact with copper(ii) sulfate, metals (e.g., sodium), oxidants (e.g., barium peroxide, barium oxide, lead dioxide, potassium permanganate, chlorine), phosphorus chlorides (e.g., phosphorus trichloride, phosphorus pentachloride). incompatible with carbonyls, pyridine. vigorous reaction with hypochlorites. when heated to decomposition it emits toxic fumes of nox. see also amines.
hazard codes:
xn: harmful 
n: dangerous for the environment
risk statements:
r5: heating may cause an explosion. 
r22: harmful if swallowed.
r37/38: irritating to respiratory system and skin.
r41: risk of serious damage to the eyes.
r43: may cause sensitization by skin contact.
r48/22: harmful: danger of serious damage to health by prolonged exposure if swallowed. 
r50: very toxic to aquatic organisms.
safety statements:
s23: do not breathe vapour. 
s26: in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
s36/37/39: wear suitable protective clothing, gloves and eye/face protection.
s47: keep at temperature not exceeding...
s61: avoid release to the environment. refer to special instructions / safety data sheets. 
s22: do not breathe dust.
ridadr: un 3082 9/pg 3
wgk germany: 3
f:
f 4.8: do not heat over 80°c.
hazardclass: 8
packinggroup: ii

Specification

General description about Hydroxylamine (CAS NO.7803-49-8) ,it is a odorless white crystalline solid. Sinks and mixes with water.
Air & Water Reactions: Decomposes rapidly at room temperature or when dissolved in hot water by internal oxidation-reduction. Reacts with water or steam to produce heat and corrosive liquids.
Reactivity Profile: It is a white solid, thermally unstable, decomposes rapidly at room temperature or when dissolved in hot water by internal oxidation-reduction. It should be stored below 10° C [Bailar, 1973, vol. 2, p. 272]. Explosive reaction with strong oxidizers (chromium trioxide, potassium dichromate) or powdered zinc upon heat. Reaction with zinc or calcium produces explosive bishydroxylamides. It ignites on contact with cupric sulfate, alkali metals (sodium, potassium), oxidants (e.g., barium oxide, barium peroxide, lead dioxide, potassium permanganate, chlorine), phosphorus trichloride and pentachloride. It reacts vigorously with hypochlorites, pyridine, carbonyls [Sax, 9th ed., 1996, p. 1875]. On contact with organic materials in thin layer (e.g., crystals on filter paper), it may ignite spontaneously in air. It explodes when heated above 70° C [Brauer, 1963, vol. 1, p. 502]. During a distillation process, an explosion occurred. Potassium hydroxide is thought to be involved in the explosion. Employees in the plant complained of chest pains and suffered chemical burns. Five people were killed by the explosion.
Health Hazard: Inhalation: Moderately toxic by inhalation and oral routes with the following symptoms possible: headache, vertigo, tinnitus, dyspnea, nausea and vomiting, cyanosis, proteinuria and hematuria, jaundice, restlessness, and convulsion. Methemoglobinemia has been reported. Eyes: Corrosive - highly irritating. Skin: Irritating or corrosive to skin. Ingestion: Moderately toxic by inhalation and oral routes with the following symptoms possible; headache, vertigo, tinnitus, dyspnea, nausea and vomiting, cyanosis, proteinuria and hematuria, jaundice, restlessness, and convulsion. Methemoglobinemia has been reported.

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