Welcome to LookChem.com Sign InJoin Free

Cas Database

4463-41-6

4463-41-6

Identification

  • Molecular Formula:C10H11BO3

  • EINECS:

Synonyms:p-Tolueneboronic acid, cyclic trimethyleneester (8CI);1,3-Propanediol cyclic p-tolueneboronate;2-(4-Methylphenyl)-1,3-dioxa-2-borinane;2-(4-Tolyl)-1,3,2-dioxaborinane;2-p-Tolyl-1,3,2-dioxaborinane;

Post Buying Request Now
Entrust LookChem procurement to find high-quality suppliers faster

Safety information and MSDS

  • Pictogram(s):IrritantXi

  • Hazard Codes:Xi

  • Signal Word:

  • Hazard Statement:

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
  • Delivery
  • Purchase
  • Manufacture/Brand:AHH
  • Product Description:4-(1,3,2-Dioxaborinan-2-yl)benzaldehyde 97%
  • Packaging:5g
  • Price:$ 650
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Apolloscientific
  • Product Description:4-Formylbenzeneboronicacid,propane-1,3-diolcyclicester
  • Packaging:500mg
  • Price:$ 29
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Apolloscientific
  • Product Description:4-Formylbenzeneboronicacid,propane-1,3-diolcyclicester
  • Packaging:1g
  • Price:$ 45
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:SynQuest Laboratories
  • Product Description:4-Formylbenzeneboronic acid, propane-1,3-diol cyclic ester
  • Packaging:1 g
  • Price:$ 50
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:SynQuest Laboratories
  • Product Description:4-Formylbenzeneboronic acid, propane-1,3-diol cyclic ester
  • Packaging:500 mg
  • Price:$ 32
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:TRC
  • Product Description:4-(1,3,2-dioxaborinan-2-yl)benzaldehyde
  • Packaging:100mg
  • Price:$ 65
  • Delivery:In stock
  • Buy Now

Relevant articles and documentsAll total 4 Articles be found

Ruthenium(0)-catalyzed sp3 C-H bond arylation of benzylic amines using arylboronates

Dastbaravardeh, Navid,Schnuerch, Michael,Mihovilovic, Marko D.

supporting information; experimental part, p. 1930 - 1933 (2012/05/31)

A Ru-catalyzed direct arylation of benzylic sp3 carbons of acyclic amines with arylboronates is reported. This highly regioselective and efficient transformation can be performed with various combinations of N-(2-pyridyl) substituted benzylamines and arylboronates. Substitution of the pyridine directing group in the 3-position proved to be crucial in order to achieve high arylation yields. Furthermore, the pyridine directing group can be removed in high yields via a two-step protocol.

Generation of organolithium compounds bearing super silyl ester and their application to Matteson rearrangement

Oda, Susumu,Yamamoto, Hisashi

supporting information, p. 8165 - 8168 (2013/08/23)

It's super-silyl-fragilithyl-ester-aryl-docious: The super silyl group is a strong protecting group for carboxylic acids and provides a method for direct lithiation that is compatible with the ester moiety. Organolithium compounds bearing a super silyl ester react with a variety of electrophiles in high yields (see scheme). The reaction of lithiated super silyl chloroacetate with a boron compound gives α-functionalization of the ester moiety by Matteson rearrangement. Copyright

Derivatization and Mass Spectrometric Investigation of Substituted Benzeneboronic Acids. The Use of Linked Scanning During Gas Chromatography Mass Spectrometry

Longstaff, Colin,Rose, Malcolm Edward

, p. 508 - 518 (2007/10/02)

Substituted benzeneboronic acids are important intermediates in the synthesis of support matrices for affinity chromatography but their analysis by mass spectrometry is hindered by thermal reactions in the ion source.A simple derivatization with 1,2- or 1

Alkynes as activators in the nickel-catalysed addition of organoboronates to aldehydes

Takahashi, Go,Shirakawa, Eiji,Tsuchimoto, Teruhisa,Kawakami, Yusuke

, p. 1459 - 1461 (2007/10/03)

Alkynes act not as substrates but as co-catalysts in the presence of a nickel catalyst, an organoboronate and an aldehyde to promote the addition reaction between the substrates in combination with H2O. The Royal Society of Chemistry 2005.

Process route upstream and downstream products

Process route

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

trimethyleneglycol
504-63-2

trimethyleneglycol

2-(p-tolyl)-1,3,2-dioxaborinane
4463-41-6

2-(p-tolyl)-1,3,2-dioxaborinane

Conditions
ConditionsYield
Indichloromethane;at 20 ℃;
96%
Inethyl acetate;for 0.5h; Ambient temperature; derivatization to boronic acids;
Withmagnesium sulfate;Indiethyl ether;at 20 ℃; for 9h;
Indichloromethane;at 20 ℃; Inert atmosphere;
2-(p-tolyl)-1,3,2-dioxaborinane
4463-41-6

2-(p-tolyl)-1,3,2-dioxaborinane

(E)-N-(4-methoxybenzylidene)benzenesulfonamide
664985-99-3

(E)-N-(4-methoxybenzylidene)benzenesulfonamide

N-((4-methoxyphenyl)(p-tolyl)methyl)benzenesulfonamide
115377-87-2

N-((4-methoxyphenyl)(p-tolyl)methyl)benzenesulfonamide

2,3-diphenyl-1,3-butadiene
2548-47-2

2,3-diphenyl-1,3-butadiene

2-(p-tolyl)-1,3,2-dioxaborinane
4463-41-6

2-(p-tolyl)-1,3,2-dioxaborinane

(Z)-2,3-diphenyl-1-(p-tolyl)-2-butene

(Z)-2,3-diphenyl-1-(p-tolyl)-2-butene

(E)-2,3-diphenyl-1-(p-tolyl)-2-butene

(E)-2,3-diphenyl-1-(p-tolyl)-2-butene

Conditions
ConditionsYield
Withtriphenylphosphine; butan-1-ol;bis(1,5-cyclooctadiene)nickel (0);In1,4-dioxane;at 100 ℃; for 2h; Title compound not separated from byproducts.;
2,3-diphenyl-1,3-butadiene
2548-47-2

2,3-diphenyl-1,3-butadiene

2-(p-tolyl)-1,3,2-dioxaborinane
4463-41-6

2-(p-tolyl)-1,3,2-dioxaborinane

(E)-2,3-diphenyl-1-(p-tolyl)-2-butene

(E)-2,3-diphenyl-1-(p-tolyl)-2-butene

2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

2-(p-tolyl)-1,3,2-dioxaborinane
4463-41-6

2-(p-tolyl)-1,3,2-dioxaborinane

2,3-dimethyl-4-(p-tolyl)-1-butene
87567-60-0

2,3-dimethyl-4-(p-tolyl)-1-butene

2,3-dimethyl-3-(p-tolyl)-1-butene

2,3-dimethyl-3-(p-tolyl)-1-butene

2,3-dimethyl-1-(p-tolyl)-2-butene

2,3-dimethyl-1-(p-tolyl)-2-butene

Conditions
ConditionsYield
Withtriphenylphosphine; butan-1-ol;bis(1,5-cyclooctadiene)nickel (0);In1,4-dioxane;at 100 ℃; for 2h; Further Variations:; Reagents; Solvents; time; Product distribution;
2-(p-tolyl)-1,3,2-dioxaborinane
4463-41-6

2-(p-tolyl)-1,3,2-dioxaborinane

(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

cyclohexenone
930-68-7

cyclohexenone

2-(p-tolyl)-1,3,2-dioxaborinane
4463-41-6

2-(p-tolyl)-1,3,2-dioxaborinane

3-(p-tolyl)cyclohexan-1-one
99495-15-5

3-(p-tolyl)cyclohexan-1-one

4-Trifluoromethylbenzaldehyde
455-19-6

4-Trifluoromethylbenzaldehyde

2-(p-tolyl)-1,3,2-dioxaborinane
4463-41-6

2-(p-tolyl)-1,3,2-dioxaborinane

(4-methylphenyl)(4-trifluoromethyl)methanol
33757-36-7

(4-methylphenyl)(4-trifluoromethyl)methanol

Conditions
ConditionsYield
93%
4-Octyne
1942-45-6

4-Octyne

benzaldehyde
100-52-7

benzaldehyde

2-(p-tolyl)-1,3,2-dioxaborinane
4463-41-6

2-(p-tolyl)-1,3,2-dioxaborinane

(Z)-1-phenyl-2-propyl-3-(p-tolyl)hex-2-en-1-ol
1043871-06-2

(Z)-1-phenyl-2-propyl-3-(p-tolyl)hex-2-en-1-ol

4-methylphenyl(phenyl)methanol
1517-63-1

4-methylphenyl(phenyl)methanol

1-methyl-4-[(1E)-1-propyl-1-penten-1-yl]benzene
42353-96-8

1-methyl-4-[(1E)-1-propyl-1-penten-1-yl]benzene

Conditions
ConditionsYield
5%
4%
79%
benzaldehyde
100-52-7

benzaldehyde

2-(p-tolyl)-1,3,2-dioxaborinane
4463-41-6

2-(p-tolyl)-1,3,2-dioxaborinane

4-methylphenyl(phenyl)methanol
1517-63-1

4-methylphenyl(phenyl)methanol

Conditions
ConditionsYield
99%

Global suppliers and manufacturers

Global( 4) Suppliers
  • Company Name
  • Business Type
  • Contact Tel
  • Emails
  • Main Products
  • Country
  • Career Henan Chemical Co
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-371-86658258
  • Emails:purchase@coreychem.com
  • Main Products:137
  • Country:China (Mainland)
  • Antimex Chemical Limied
  • Business Type:Lab/Research institutions
  • Contact Tel:0086-21-50563169
  • Emails:anthony@antimex.com
  • Main Products:151
  • Country:China (Mainland)
close

Please post your buying leads,so that our qualified suppliers will soon contact you!

*Required Fields

CAS No.:
* Product Name:
* Your email:

Your email will be used to sign-in to LookChem.com
* Requirements:
* Valid for:
 
Post Buying Request Now
close
Remarks: The blank with*must be completed