CAS No.7758-99-8,Sulfuric acidcopper(2+) salt (1:1), hydrate (1:5) Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	7758-99-8
Name:	Sulfuric acidcopper(2+) salt (1:1), hydrate (1:5)
Article Data:	457
Cas Database

Formula:	CuSO₄^.5(H₂O)
Molecular Weight:	159.61
Synonyms:	Sulfuricacid copper(2+) salt (1:1), pentahydrate (8CI,9CI);Copper sulfate (CuSO4)pentahydrate;Copper sulfate pentahydrate;Copper(2+) sulfate pentahydrate;Copper(II) sulfate pentahydrate;Cupric sulfate pentahydrate;Copper(Ⅱ)sulfate;copper sulphate;
EINECS:	231-847-6
Density:	2.284 g/cm³
Melting Point:	110 °C (dec.)(lit.)
Boiling Point:	330oC at 760 mmHg
Flash Point:	N/A
Solubility:	320 g/L (20 °C) in water
Appearance:	Blue crystalline granules or powder
Hazard Symbols:	Xn, N, Xi
Risk Codes:	22-36/38-50/53-52/53-36-36/37/38-20/21/22
Safety:	22-60-61-26-36
Transport Information:	UN 3288 6.1/PG 3
PSA:	134.79000
LogP:	-0.58120

Synthetic route

: copper(I) oxide

: 77-78-1
dimethyl sulfate

: 7758-99-8
copper(II) sulfate

Conditions

Conditions	Yield
at 160℃; for 0.166667h; Inert atmosphere;	94%

: 22205-45-4
copper(I) sulfide

A: copper(I) oxide

B: 7758-99-8
copper(II) sulfate

Conditions

Conditions	Yield
With oxygen In neat (no solvent) byproducts: SO2; at 500°C, O2-N2-mixtures with up to 60% O2;;	A 50% B n/a
With O2 In neat (no solvent) byproducts: SO2; at 500°C, O2-N2-mixtures with up to 60% O2;;	A 50% B n/a
With oxygen byproducts: SO2; over 500°C;

: copper (II) carbonate hydroxide

: 7664-93-9
sulfuric acid

: 7758-99-8
copper(II) sulfate

Conditions

Conditions	Yield
In water

: Cu(2+)*2Cu(1+)*2SO3(2-)=Cu(CuSO3)2

A: 7758-99-8
copper(II) sulfate

B: copper(II) oxide

Conditions

Conditions	Yield
In neat (no solvent) byproducts: SO3(2-); thermal decompn., corundum crucible, 226°C, 260-375°C;

: 7732-18-5
water

: copper(II) sulfide

: 10028-15-6
ozone

: 7758-99-8
copper(II) sulfate

Conditions

Conditions	Yield
In water

...Expand

: copper(II) sulfide

: 10028-15-6
ozone

: 7758-99-8
copper(II) sulfate

Conditions

Conditions	Yield
In neat (no solvent) rapid oxidation to CuSO4;;
In neat (no solvent) oxidation;;
In neat (no solvent) rapid oxidation to CuSO4;;
In neat (no solvent) oxidation;;

: 7732-18-5
water

: 7757-82-6
sodium sulfate

A: 7758-99-8
copper(II) sulfate

B: 1310-73-2
sodium hydroxide

Conditions

Conditions	Yield
In not given Electrolysis; arrangement with diaphragms; Cu anode; liquid film between 2 porous walls of separation between anode and cathode region, regenaration by circulation;;

...Expand

: Cu2(2+)*SO4(2-)=Cu2SO4

A: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

B: 7758-99-8
copper(II) sulfate

Conditions

Conditions	Yield
In sulfuric acid diln. of H2SO4;
In sulfuric acid aq. H2SO4; diln. of H2SO4;

: iron sulfide

: 80937-33-3
oxygen

: copper(II) oxide

A: iron(III) oxide

B: 7758-99-8
copper(II) sulfate

...Expand

: iron(III) sulfate

: 22205-45-4
copper(I) sulfide

: iron sulfide

: 7647-14-5
sodium chloride

: copper(II) oxide

A: iron(III) oxide

B: 7758-99-8
copper(II) sulfate

C: copper dichloride

Conditions

Conditions	Yield
With sulfur dioxide; oxygen byproducts: Na2SO4;
With sulfur dioxide; oxygen byproducts: Na2SO4;

...Expand

Raw Materials

77-78-1

142-71-2

Downstream Products

601-57-0

617-07-2

144-62-7

1453-82-3

100612-91-7

108-86-1

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Consensus Reports

Copper and its compounds are on the Community Right-To-Know List.

Standards and Recommendations

ACGIH TLV: TWA (fume) 0.2 mg/m³; (dust, mist) 1 mg(Cu)/m³

Specification

The Copper sulfate pentahydrate, with the CAS registry number 7758-99-8, is also known as Copper (II) sulfate.It belongs to the product categories of Metabolites;Metal and Ceramic Science;Molluscicides;Pesticides;Pesticides &;Salts;Ultra-High Purity Materials. This chemical's molecular formula is CuSO₄.5(H₂O) and molecular weight is 249.68. What's more,Its systematic name is Copper sulfate pentahydrate.

Physical properties about Copper sulfate pentahydrate are: (1)mp: 110 °C (dec.)(lit.); (2)density: 2.284; (3)vapor pressure: 7.3 mm Hg ( 25 °C); (4)storage temp: Store at RT; (5)solubility: 320 g/L (20°C); (6)Water Solubility: 320 g/L (20 oC); (7)Merck: 14,2653.

Copper sulfate pentahydrate can be dehydrated by heating. Serves as a weak oxidizing agent. Causes hydroxylamine to ignite. Gains water readily. The hydrated salt is vigorously reduced by hydroxylamine [Mellor 8:292(1946-1947)]. Both forms are incompatible with finely powdered metals. Both are incompatible with magnesium, corrode steel and iron, may react with alkalis, phosphates, acetylene gas, hydrazine, or nitromethane, and may react with beta-naphthol, propylene glycol, sulphathiazole and triethanolamine if the pH exceeds 7 . Both act as acidic salts, corrode metals and irritate tissues.

The Copper sulfate pentahydrate is harmful by inhalation, in contact with skin and if swallowed. It is irritating to eyes, respiratory system and skin.The Copper sulfate pentahydrate is very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment, so it should be avoided release to the environment. Refer to special instructions safety data sheet .This material and/or its container must be disposed of as hazardous waste.When you use it,wear suitable protective clothing.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Do not breathe dust.

You can still convert the following datas into molecular structure:
(1)SMILES:O.O.O.O.O.[O-]S(=O)(=O)[O-].[Cu+2];
(2)Std. InChI:InChI=1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2;
(3)Std. InChIKey:JZCCFEFSEZPSOG-UHFFFAOYSA-L;

The toxicity data of Copper sulfate pentahydrate as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
bird - wild	LDLo	oral	300mg/kg (300mg/kg)		Australian Veterinary Journal. Vol. 16, Pg. 147, 1940.
bird - wild	LDLo	oral	300mg/kg (300mg/kg)	BEHAVIORAL: COMA BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)	Australian Veterinary Journal. Vol. 16, Pg. 147, 1940.
dog	LDLo	oral	60mg/kg (60mg/kg)		"Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
domestic animals - goat/sheep	LDLo	oral	5mg/kg (5mg/kg)	GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" BLOOD: HEMORRHAGE BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)	Journal of Comparative Pathology. Vol. 82, Pg. 47, 1972.
duck	LDLo	oral	600mg/kg (600mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: COMA	Australian Veterinary Journal. Vol. 16, Pg. 147, 1940.
guinea pig	LDLo	subcutaneous	62mg/kg (62mg/kg)	BEHAVIORAL: COMA GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" AUTONOMIC NERVOUS SYSTEM: OTHER (DIRECT) PARASYMPATHOMIMETIC	British Medical Journal. Vol. 2, Pg. 217, 1913.
human	LDLo	oral	1088mg/kg (1088mg/kg)	BEHAVIORAL: COMA BLOOD: OTHER HEMOLYSIS WITH OR WITHOUT ANEMIA	Indian Practitioner. Vol. 18, Pg. 807, 1965.
human	TDLo	oral	272mg/kg (272mg/kg)	KIDNEY, URETER, AND BLADDER: OTHER CHANGES BLOOD: OTHER HEMOLYSIS WITH OR WITHOUT ANEMIA	Indian Practitioner. Vol. 18, Pg. 807, 1965.
mammal (species unspecified)	LD50	intraperitoneal	7500ug/kg (7.5mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS GASTROINTESTINAL: NAUSEA OR VOMITING	Journal of Animal Science. Vol. 55, Pg. 337, 1982.
man	LDLo	unreported	221mg/kg (221mg/kg)		"Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970.
man	TDLo	oral	429mg/kg (429mg/kg)	VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION BEHAVIORAL: SLEEP	Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 41, Pg. 193, 1999.
mouse	LD50	intraperitoneal	33mg/kg (33mg/kg)		Biochemical Pharmacology. Vol. 14, Pg. 289, 1965.
pigeon	LDLo	oral	1gm/kg (1000mg/kg)		Australian Veterinary Journal. Vol. 16, Pg. 147, 1940.
pigeon	LDLo	oral	1gm/kg (1000mg/kg)	BEHAVIORAL: COMA BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)	Australian Veterinary Journal. Vol. 16, Pg. 147, 1940.
rat	LD50	intraperitoneal	18700ug/kg (18.7mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 53(4), Pg. 78, 1988.
rat	LD50	oral	300mg/kg (300mg/kg)		"Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 2, Pg. 182, 1977.
rat	LD50	skin	> 2gm/kg (2000mg/kg)		Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 18, Pg. S161, 1993.

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